This geophysical study was carried out to determine the occurrence of phosphate nodules in the Oshoshun Formation of the Dahomey Basin, Southwestern Nigeria. The electrical resistivity method, comprising 1D vertical electrical sounding (VES; using Schlumberger array) and 2D geoelectrical imaging (using Wenner array), was used to determine the nature and depth of occurrence of the phosphate nodules. Six profile lines were established within the study area, and inverted sections were generated from the apparent resistivity data using DIPRO inversion algorithm. Five VES points were also acquired in the study area, and Win-Resist programme was used to process and interpret the field resistivity data. Four pits were dug along the profiles to verify the interpreted results. The results obtained by both techniques reveal similar geoelectric units: the top soil, clay, clayey sand and clay at different depths. These layers host pockets of phosphate nodules (78–≥651 Ωm) with varying thicknesses. The strong correlation between the lithology profiles obtained from the pits and the interpreted results of the inverted apparent resistivity sections demonstrates the efficacy of the electrical resistivity method in characterising phosphate occurrence within the formation.