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Effect of Sm concentration on optical and electrical properties of CdSe nanocrystalline thin film

Abstract

Present paper reports optical and electrical properties of samarium doped CdSe nanocrystalline thin film which was grown on a glass substrate by chemical bath deposition method (CBD). X-ray diffraction (XRD) analysis revealed that the deposited films were nanocrystalline with sphalerite cubic structure. The average crystallite size calculated from FWHM of XRD peaks was found to be 10.11 nm. The bandgap of the Sm doped CdSe nanocrystalline thin films was calculated to be 1.91 eV to 2.22 eV. The optical absorption edge of undoped (pure) and Sm doped CdSe films was obtained between 650 nm to 640 nm showing blue shift as compared to bulk CdSe. Sm doping further enhanced the photoconductivity of these films. The I-V characteristic confirmed the suitability of prepared films for photosensor applications.

Open access
Estimation of Magnetic Contact Location and Depth of Magnetic Sources in a Sedimentary Formation

Abstract

The aeromagnetic data of Idogo, Southwestern Nigeria, have been used to study the lithology and to determine the magnetic source parameters within Idogo and its environs. Idogo lies between latitudes 6°30′N and 7°00′N and between longitudes 2°30′E and 3°00′E. The magnetic anomaly map, the regional geology, the analytic signal and the local wavenumber were used to identify the nature and depth of the magnetic sources in the region. Data enhancement was carried out to delineate the residual features relative to the strong regional gradients and intense anomalies due to the basin features. The estimated basement depth using the horizontal gradient method revealed depths ranging between 0.55 km and 2.49 km, while the analytic signal amplitude and local wavenumber methods estimated depth to the magnetic sources to range from 0.57 km to 4.22 km and 0.96 km to 2.43 km, respectively. Depth computations suggested the presence of both shallow and deep sources. The total magnetic intensity values ranged from 3.1 nT to 108.3 nT. The area shows magnetic closures of various sizes in different parts of the area trending West, with prominence at the centre and distributed East–West.

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Estimation of optical parameters of silicon single crystals with different orientations

Abstract

Optical properties of Si single crystals with different orientations (1 0 0) and (1 1 1) were investigated using spectrophotometric measurements in a spectral range of 200 nm to 2500 nm. The data of optical absorption revealed an indirect allowed transition with energy gap of 1.1 ± 0.025 eV. An anomalous dispersion in refractive index. The normal dispersion of the refractive index was discussed according to Wemple-DiDomenico single oscillator model. The oscillator energy Eo, dispersion energy Ed, high frequency dielectric constant ∈, lattice dielectric constant ∈L and electronic polarizability α e were estimated. The real ∈1 and imaginary ∈2 parts of dielectric constant were also determined.

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Geotechnical Terrain Models and Types of Instabilities in the Durmitor Flysch Complex

Abstract

The Durmitor flysch complex represents a specific formation both in lithological and engineering geological sense. In the engineering geological sense this lithological formation is characterized by anisotropic and heterogeneous geotechnical properties, which depend on the dominant members within each individual package, as well as their spatial position.The Durmitor flysch complex consists of five superposition bed packages, which are mutually substantially different in their lithological, hydrogeological and geotechnical properties. For the first time in geological literature, this paper distinguishes five types of terrain construction within the Durmitor flysch complex. Contemporary geodynamic processes and their character within the flysch formation are defined. Particular emphasis is put on landslides, which represent a contemporary geodynamic phenomenon with certain specificities.

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High resolution airborne radiometric and magnetic studies of ilesha and its environs, southwestern Nigeria

Abstract

The study of the nature of distribution of natural radioelements in Ilesha and its environs with its geological structure has been studied using aeroradiometric data. Aeromagnetic data have also been subjected to three automated gradient techniques to delineate the sub-surface structure of the study area. From the study, it can be found that maximum values of “eU” (ppm) and “eTh” (ppm) fall within the branded gneiss, whereas the maximum value of K (%) falls within porphyritic granite regions. eTh had the highest radioactive content. The environmental dose rate of Ilesha was between 0.1817 and 3.9296 msv/yr. Although there were extreme values, but the mean dose rate was 0.522 ± 0.310 msv/yr (within acceptable safe limit of 1.0 msv/yr). eU/K, eU/eTh and eTh/K ratios were analysed for enrichment or depletion of radioisotopes. eU/eTh >1 showed uranium depletion, while eTh >2 showed eTh enrichment. The magnetic intensity values ranged from -79.41 to 140.93 nT. The horizontal gradient method (HGM) and analytic signal amplitude (ASA) revealed that depth to magnetic sources ranged from 0.478 to 4.112 km and 0.348 to 2.551 km, respectively, whereas local wavenumber (LWN) depth ranged from 0.478 to 5.48 km, which overestimated those compared using HGM and ASA functions. The apparent susceptibility ranged from -0.00325 to 0.00323 SI, showing that ferromagnetic and diamagnetic mineral ranges control apparent susceptibility in Ilesha.

Open access
Influence of bath temperature on microstructure and NH3 sensing properties of chemically synthesized CdO thin films

Abstract

Cadmium oxide (CdO) thin films were synthesized using chemical bath deposition (CBD) method from aqueous cadmium nitrate solution. The bath temperatures were maintained at room temperature (25 °C) and at higher temperature (80 °C). The structural studies revealed that the films showed mixed phases of CdO and Cd(OH)2 with hexagonal/monoclinic crystal structure. Annealing treatment removed the hydroxide phase and the films converted into pure CdO with cubic, face centered crystal structure. SEM micrographs of as-deposited films revealed nanowire-like morphology for room temperature deposited films while nanorod-like morphology for high temperature deposited films. However, cube-like morphology was observed after air annealing. Elemental composition was confirmed by EDAX analysis. Band gap energies of the as-deposited films varied over the range of 3 eV to 3.5 eV, whereas the annealed films showed band gap energy variation in the range of 2.2 eV to 2.4 eV. The annealed films were successfully investigated for NH3 sensing at different operating temperatures and at different gas concentrations. The room temperature synthesized film showed a response of 17.3 %, whereas high temperature synthesized film showed a response of 13.5 % at 623 K upon exposure to 24 ppm of NH3.

Open access
Investigation of Land Use Types on Physical and Chemical Properties of Soil in a Basement Terrain

Abstract

We assessed the effect of different land use types on the physical and chemical properties of soil. We analysed three cases. Nine soil samples were taken at different depths (0–10, 10–20 and 20–30 cm) from three locations, namely, sawmill, dumpsite and market. Analyses were carried out to determine the influences on the physical and chemical properties of the soil. All the land types had considerably high sand contents, with minor silt and clay. Available phosphorus and the exchangeable bases were significantly (p ≤ 0.05) affected by land use and soil depth. Moisture content (p ≤ 0.05) was significantly affected by land use, while bulk density (p ≤ 0.01) was significantly affected by soil depth. Soil organic matter and carbon were also generally low in all three locations. Consequently, ameliorative land management practices have to be adopted to prevent nutrient loss and land degradation.

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Modelling of electronic and optical properties of Cu2SnS3 quantum dots for optoelectronics applications

Abstract

Copper tin sulfide (Cu2SnS3) is a unique semiconductor, whose nanocrystals have attracted researchers’ attention for its tunable energy bandgap and wavelength in visible and near infrared range. Quantum dots which are fabricated from this material are highly suitable for optoelectronics and solar cell applications. This paper discusses the tunable energy bandgap, exciton Bohr radius and wavelength range of wurtzite structure of Cu2SnS3 quantum dots to assess the opportunity to use them in optoelectronics applications. The considerations show that the mole fraction of copper increases as energy bandgap decreases and tunable energy bandgap of this quantum dot material is inversely proportional to the wavelength.

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New Method of Visibility Network and Statistical Pattern Network Recognition Usage in Terrain Surfaces

Abstract

Many problems in the analysis of natural terrain surface shapes and the construction of terrain maps to model them remain unsolved. Almost the whole process of thematic interpretation of aerospace information consists of a step-by-step grouping and further data conversion for the purpose of creating a completely definite, problematically oriented picture of the earth’s surface. In this article, we present application of a new method of drawing 3D visibility networks for pattern recognition and its application on terrain surfaces. For the determination of complexity of 3D surface terrain, we use fractal geometry method. We use algorithm for constructing the visibility network to analyse the topological property of networks used in complex terrain surfaces. Terrain models give a fast overview of a landscape and are often fascinating and overwhelmingly beautiful works by artists who invest all their interest and an immense amount of work and know-how, combined with a developed sense of the portrayed landscape, in creating them. At the end, we present modelling of terrain surfaces with topological properties of the visibility network in 3D space.

Open access
Production of zinc oxide thin films and crystals in different deposition times and investigation of their structural, optical and electronic properties

Abstract

An aqueous colloidal solution was prepared at 80 °C and pH = 9 from suitable chemical compounds to produce zinc oxide (ZnO) crystals and thin films. The ZnO crystals were grown in the colloidal solution under special conditions. Their micrographs showed ZnO rods with hexagonal structure. The number of the rods, increased over time. The ZnO thin films were produced on glass substrates in the same colloidal solution using the chemical bath deposition (CBD) method in different deposition times. The produced films were post-annealed for about one hour at 400 °C. Crystalline structure, phase transitions and nanostructure of the films were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM). ZnO wurtzite structure was dominant, and by increasing the deposition time, the films became more crystalline. Nanostructure of the films changed from rod to wire and transformed into pyramid-like structures. Also, morphology of the films changed and re-nucleation ocurred. Optical reflectance was measured in the wavelength of 300 nm to 800 nm with a spectrophotometer. Other optical properties and optical band gaps were calculated using Kramers-Kronig relation on reflectivity curves. Second harmonic generation was calculated by Z-scan technique. Nonlinear refraction and real part of susceptibilities were obtained. Both positive and negative nonlinear refractions appeared in the ZnO films. It is important for the use in optoelectronic devices. Electronic properties were assessed by the full potential linearized augmented plane wave (FP-LAPW) method, within density functional theory (DFT). In this approach, the generalized gradient approximation (GGA) was used for the exchange-correlation potential calculation. The band gap structure and density of states were calculated.

Open access