Ingars Reinholds, Iveta Pugajeva and Vadims Bartkevičs
This research demonstrates the development of reliable multi-component methods for the detection of antibiotic residues in environmental biota. The efficiency of analytical performance of ultra high performance liquid chromatography (UHPLC) techniques with triple quadrupole (QqQ-MS/MS) and Orbitrap high-resolution mass spectrometry (Orbitrap-HRMS) detectors is discussed. Antibiotic residues in biota samples collected in Latvia were analysed. The contamination status was determined as rather low within acceptable levels set by the European Union Regulations.
Olga Muter, Andrejs Bērzinš, Tūrs Selga, Ruta Švinka and Visvaldis Švinka
Ceramic granules fabricated from Quaternary clay at 1200°C were tested for their flotation ability in a water model system containing silicone oil. The presence of oil in the liquid phase improved flotation of granules, probably due to sorption of oil by ceramics. Coating of granules with SiO2 resulted in decreased flotation ability, irrespectively of the presence of oil. Granules were shown to be appropriate for bacterial colonization.
Lauris Rupeks, Viktor Filipenkov, Ivars Knets, Visvaldis Vitins, Marina Sokolova, Liga Stipniece and Mara Pilmane
Hydroxyapatite is used for bone reconstruction, in order to improve its mechanical properties different substances can be added. In our study new biomaterial is created from deproteinised hydroxyaptite and endodentic cement, its mechanical properties were tested. Material was implanted subcutaneous in rats, then histological and biocompatability tests were performed. Results indicate that stuff has good mechanical properties, short setting time and gradual resorption creating porosity and ability to integrate in bone.
Raw clays from the Baltic region are characterized as smectite containing clays with significant amount of naturally occurring impurities that limiting the potential applications of crude Baltic clay resources. Purification of clay samples from Šaltiškių deposit (Venta basin) was carried out by varied concentration hydrochloric acid solutions and resulted in fine removal of carbonates and iron oxide. The main idea of this work is to widen the possible applications of local clay resources providing a new type of raw material for further organoclay production.
The aim of this study was to detect major whey proteins α-lactalbumin and β-lactoglobulin by reversed-phase high-performance liquid chromatography (RP-HPLC). RPHPLC methods were developed using the column YMC Pack-C4, which enabled the separation of whey proteins within 30 min. Mobile phase was acetonitrile/water/0.1% trifluoroacetic acid (TFA) with gradient elution, flow rate was 1.0 mL·min−1, and the detection wavelength was 210 nm. Column temperature was 40°C and injection volume was 20 μL.
Milk samples contained α-lactalbumin and total β-lactoglobulin: No. 1 - 1500 mg·L−1 and 3600 mg·L−1; No. 2 - no α-lactalbumin and 450 mg·L−1 total β-lactoglobulin; No. 3 - 800 mg·L−1 and 94 mg·L−1, respectively.
Water-soluble polymer, cationic poly(N-[3-hexyldimethyl-aminopropyl] methacrylamide bromide) (PHDAPMAA), is synthesized by radical polymerization and studied in terms of its solubility, viscosity, surface tension and conductivity. Viscometry and surface tension measurements confirmed that intramolecular hydrophobic microdomains were formed by the pendent alkyl chains. Conductivity of cationic polymer in aqueous solution was determined. Variation of conductivity versus concentration in investigated system exhibits a typical polyelectrolyte behaviour.
Christo Angelov, Todor Arsov, Ilia Penev, Nina Nikolova, Ivo Kalapov and Stefan Georgiev
Trans boundary and local pollution, global climate changes and cosmic rays are the main areas of research performed at the regional Global Atmospheric Watch (GAW) station Moussala BEO (2925 m a.s.l., 42°10’45’’ N, 23°35’07’’ E). Real time measurements and observations are performed in the field of atmospheric chemistry and physics. Complex information about the aerosol is obtained by using a threewavelength integrating Nephelometer for measuring the scattering and backscattering coefficients, a continuous light absorption photometer and a scanning mobile particle sizer. The system for measuring radioactivity and heavy metals in aerosols allows us to monitor a large scale radioactive aerosol transport. The measurements of the gamma background and the gamma-rays spectrum in the air near Moussala peak are carried out in real time. The HYSPLIT back trajectory model is used to determine the origin of the data registered. DREAM code calculations  are used to forecast the air mass trajectory. The information obtained combined with a full set of corresponding meteorological parameters is transmitted via a high frequency radio telecommunication system to the Internet.
Abstract: Chemical modification of alginic acid has been done by ultrasonic irradiation to obtain its methylated, ethylated and isopropylated derivatives. The influence of ultrasonic frequency and power on esterification process of alginic acid has been investigated. Alginate derivatives have been characterized by degree of esterification (DE) and IR-FT spectroscopy. It has been found that 45 kHz ultrasonic frequency accelerated modification process as reduced the reaction time from 16 hours to 2 hours. The obtained results showed that ultrasound irradiation increased the reaction efficiency in methanol and depended on the ratio of the M/G.
Dilyana Stefanova Ivanova, Jana Krumova Angarska and Emil Deyanov Manev
The critical thickness (hcr) for foam films of n-dodecyl β-D maltoside (C12G2) and of its mixed solutions with dodecanol (C12Е0), hexaethyleneglycol dodecyl ether (C12E6) and dodecyl trimethylammonium bromide (C12TAB) of different molar ratio (50:1; 1:1;1:50) at low and high ionic strength was measured interferometrically. It was found that the hcr increases with the increase of the film radius independently of solutions composition. At low ionic strength the type of surfactant affects the critical thickness and the equilibrium state of the film. hcr for the films of mixture with C12E0 increases with the increase of the total surfactant concentration, while hcr for the films of mixture with C12TAB decreases. For the values of the critical thicknesses for films from individual surfactant solutions the following sequence hcr (C12TAB) > hcr (C12E6) > hcr (C12G2) is found. At high ionic strength the quantity of nonionic additive does not substantially affect the value of hcr, while the quantity of ionic additive influences it by two different ways (i) in 50:1 mixture C12TAB supports C12G2 in the reducing of negative charge; (ii) in 1:1 mixture C12TAB recharges the film surfaces.
Cultural heritage of the European civilization constitutes cultural and spiritual property of the ancestors, as well as current generations of the Varna city. It represents both material and non-material value, defines the European culture. It includes all the environmental consequences arising from the interaction between the man and the surroundings over the course of history. Assessment of tourist potential of Varna performed on 9-14th September, 2014, by the members of the “European Traveler” scientific circle, students of tourist and recreation, as well as heritage and culture tourism at Kazimierz Wielki University in Bydgoszcz, made it possible to identify the main points of tourist recognizability in relation to the city and region. The staid points are predominantly based on the unique cultural assets of the city and the region - in large measure related to the origins of the European civilization - as well as current cultural events organized in the city.