Optical properties of Si single crystals with different orientations (1 0 0) and (1 1 1) were investigated using spectrophotometric measurements in a spectral range of 200 nm to 2500 nm. The data of optical absorption revealed an indirect allowed transition with energy gap of 1.1 ± 0.025 eV. An anomalous dispersion in refractive index. The normal dispersion of the refractive index was discussed according to Wemple-DiDomenico single oscillator model. The oscillator energy Eo, dispersion energy Ed, high frequency dielectric constant ∈∞, lattice dielectric constant ∈L and electronic polarizability αe were estimated. The real ∈1 and imaginary ∈2 parts of dielectric constant were also determined.
The main aim of this article is to demonstrate that in a dynamically changing business environment, an organization should focus on embracing imitation strategies such as a safer form of building up its market position. The author addresses issues of innovation and imitation, provides definitions and defines realistic conditions and advantages of imitation strategies. Innovation does not guarantee a company's market success. The research conducted has shown that imitation is not only a commonly used strategy of creating competitiveness, but it is also the foundation of many firms’ success stories. Innovative imitation, technological diffusion, creative imitation should be treated equally as innovation – as a another development strategy, different form of strategy implementation, assuming less risk and wider market access with less risk and cost.
Maksym Lobodanov, Pavlo Vegera and Zinoviy Blikharskyy
In current economic trends, changes in construction using are required. It usually leads to changes in value and type of the working load on building structures, with the requirement to rate the technical state and replace or strengthen the elements. An important aspect of determining the residual bearing capacity of damaged bending reinforced concrete elements is the research concerning the influence of difference defects and damages on the change of strength and deformability. In the article main types of damages and defects, methods of studies of damaged reinforced concrete elements and the expediency of usage of this elements are described. However, most methods are suitable only for certain defects and damages due to the large complexity of calculations and the consideration of multifactoriality. Significant complexity of a single method for calculating damaged elements depends on the possible changing stress strain state of an element in combination with certain defects and damages, the presence of a non-complete separation where during loading or alteration of the damaged element the fractions become included in the work, reinforced concrete is the composite material which carrying complexity in calculating the joint work of its components.
A.K. Sharma, S.S. Potdar, M.A. Yewale, Deepak B. Shirgaonkar, K.S. Pakhare, B.M. Sargar, M.V. Rokade and U.M. Patil
Cadmium oxide (CdO) thin films were synthesized using chemical bath deposition (CBD) method from aqueous cadmium nitrate solution. The bath temperatures were maintained at room temperature (25 °C) and at higher temperature (80 °C). The structural studies revealed that the films showed mixed phases of CdO and Cd(OH)2 with hexagonal/monoclinic crystal structure. Annealing treatment removed the hydroxide phase and the films converted into pure CdO with cubic, face centered crystal structure. SEM micrographs of as-deposited films revealed nanowire-like morphology for room temperature deposited films while nanorod-like morphology for high temperature deposited films. However, cube-like morphology was observed after air annealing. Elemental composition was confirmed by EDAX analysis. Band gap energies of the as-deposited films varied over the range of 3 eV to 3.5 eV, whereas the annealed films showed band gap energy variation in the range of 2.2 eV to 2.4 eV. The annealed films were successfully investigated for NH3 sensing at different operating temperatures and at different gas concentrations. The room temperature synthesized film showed a response of 17.3 %, whereas high temperature synthesized film showed a response of 13.5 % at 623 K upon exposure to 24 ppm of NH3.
The key to the functioning of enterprises in today's market is the concept of flexibility, which is mainly associated with adapting to very dynamically changing customer requirements. The basis for this approach is, among others, the realisation of serial production, products created for the customer's order in the quantity and time defined in orders. The LEAN Managemnt and LEAN production approach is a solution dedicated to meeting market assumptions. The LEAN concept, which both in the organization of production and management is focused on dynamic response to changes in the environment. The term LEAN represents numerous improvements to the organization, tools and techniques used to reduce and eliminate individual processes (or parts thereof) that are unnecessary activities. The key to analysing entire processes and defining unnecessary activities is thorough observation and selection of dedicated solutions. In the set of LEAN tools, you can find a lot of possibilities, from organization of a workstation itself, to a thorough quantitative analysis of times and process sequences, from simple facilities to complex technological solutions. The article presents the results of the assembly process analysis, indicates the point of product differentiation (marking for the client) and presents the map of organizational and preparatory activities for this process. The presented results are part of the activities within organization of the LEAN approach, currently having priority for the Research entity organisation improvement team.
Copper tin sulfide (Cu2SnS3) is a unique semiconductor, whose nanocrystals have attracted researchers’ attention for its tunable energy bandgap and wavelength in visible and near infrared range. Quantum dots which are fabricated from this material are highly suitable for optoelectronics and solar cell applications. This paper discusses the tunable energy bandgap, exciton Bohr radius and wavelength range of wurtzite structure of Cu2SnS3 quantum dots to assess the opportunity to use them in optoelectronics applications. The considerations show that the mole fraction of copper increases as energy bandgap decreases and tunable energy bandgap of this quantum dot material is inversely proportional to the wavelength.
Carbon-epoxy composite materials, due to their high strength in relation to mass, are increasingly used in the construction of aircraft structures, however, they are susceptible to a number of damages. One of the most common is delamination, which is a serious problem in the context of safe operation of such structures. As part of the TEBUK project, the Institute of Aviation has developed a methodology for forecasting the propagation of delamination. In order to validate the proposed method, an aerial structure demonstrator, modelled on the horizontal stabilizer of the I-23 Manager aircraft, was carried out. However, in order to carry out the validation, it was necessary to "simplify" the demonstrator model. The paper presents a numerical analysis conducted in order to separate from the TEBUK demonstrator model a fragment of the structure, which was used to study the delamination area, as an equivalent of the whole demonstrator. Subcomponent selection was carried out in several stages, narrowing down the analysed area covering delamination in subsequent steps and verifying the compliance of specific parameters with the same parameters obtained in a full demonstrator model. The parameters compared were: energy release rate values on the delamination front line and strain values in the delamination area. The numerical analyses presented in the paper were performed with the use of the MSC.Marc/Mentat calculation package. As a result of the analyses, a fragment of the structure was selected, which allows to significantly reduce the time and labour consumption of the production of the studied object, as well as to facilitate experimental research.
Stratospheric balloons are very important sources for space and terrestrial observation experiments in many disciplines. Instruments developed for astrophysical measurements are usually reusable. It is also possible to observe both hemispheres including observations from the polar and equatorial regions for thirty days or even longer. On the other hand the UV atmospheric transmittance window was used for the astrophysical observations less often than visible optical bands. At the end of the 2017 there are a few scientific groups working on near-UV or UV spectrographs and cameras for balloon flights.
In this paper we are discussing the possibility of ultraviolet measurement of Enceladus, an icy Saturnian moon, surface reflectance between 200 and 400 nm from the 20-50 km altitudes. At visible and near infrared optical channels Enceladus’ reflectance is very high (near 1.0). This value is consistent with a surface composed of water ice, however at some ultraviolet wavelengths Enceladus reflectance is lower than it would be expected for this type of surface. The scientific research done in the last decade was focused on H2O, NH3, and tholin particles detection on the Enceladus’ surface as a reason of low UV reflectance phenomenon. Continuous observation of Enceladus’ UV reflectance variability from stratospheric balloons may be interesting and may give us the proof of the presence of biomarkers or/and tholin particles.
An aqueous colloidal solution was prepared at 80 °C and pH = 9 from suitable chemical compounds to produce zinc oxide (ZnO) crystals and thin films. The ZnO crystals were grown in the colloidal solution under special conditions. Their micrographs showed ZnO rods with hexagonal structure. The number of the rods, increased over time. The ZnO thin films were produced on glass substrates in the same colloidal solution using the chemical bath deposition (CBD) method in different deposition times. The produced films were post-annealed for about one hour at 400 °C. Crystalline structure, phase transitions and nanostructure of the films were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM). ZnO wurtzite structure was dominant, and by increasing the deposition time, the films became more crystalline. Nanostructure of the films changed from rod to wire and transformed into pyramid-like structures. Also, morphology of the films changed and re-nucleation ocurred. Optical reflectance was measured in the wavelength of 300 nm to 800 nm with a spectrophotometer. Other optical properties and optical band gaps were calculated using Kramers-Kronig relation on reflectivity curves. Second harmonic generation was calculated by Z-scan technique. Nonlinear refraction and real part of susceptibilities were obtained. Both positive and negative nonlinear refractions appeared in the ZnO films. It is important for the use in optoelectronic devices. Electronic properties were assessed by the full potential linearized augmented plane wave (FP-LAPW) method, within density functional theory (DFT). In this approach, the generalized gradient approximation (GGA) was used for the exchange-correlation potential calculation. The band gap structure and density of states were calculated.
Jian Chen, Xiongfei Li, Wei Li, Cong Li, Baoshan Xie, Shuowei Dai, Jian-Jun He and Yanjie Ren
Quasi-static uniaxial compressive tests of open-cell copper (Cu) foams (OCCF) were carried out on an in-situ bi-direction tension/compress testing machine (IBTC 2000). The effects of strain rate, porosity and pore size on the energy absorption of open-cell copper foams were investigated to reveal the energy absorption mechanism. The results show that three performance parameters of open-cell copper foams (OCCF), involving compressive strength, Young modulus and yield stress, increase simultaneously with an increase of strain rate and reduce with increasing porosity and pore size. Furthermore, the energy absorption capacity of OCCF increases with an increase of porosity and pore size. However, energy absorption efficiency increases with increasing porosity and decreasing pore size. The finite element simulation results show that the two-dimensional stochastic model can predict the energy absorption performance of the foam during the compressive process. The large permanent plastic deformation at the weak edge hole is the main factor that affects the energy absorption.