Co–Zn nanocrystalline ferrites with chemical composition Co0:5Zn0:5Fe2O4 were synthesized by sol-gel and combustion methods. The sol-gel method was carried out in two ways, i.e. based on chelating agents PVA and PEG of high and low molecular weights. In auto-combustion method, the ratio of citric acid to metal nitrate was taken as 1:1, while in sol-gel method the chelating agents were taken based on oxygen balance. All the three samples were studied by thermogravimetric and differential thermal analysis for the identification of phase formation and ferritization temperature. The synthesized samples were characterized by powder X-ray diffraction and FT-IR spectroscopy without any thermal treatment. The measured lattice constants and observed characteristic IR absorption bands of the three samples are in good agreement with the reported values showing the formation of a cubic spinel structure. The crystallite sizes of all samples were determined using high intensity peaks and W-H plot. Size-Strain Plot method was also implemented since two of the samples showed low crystallite sizes. The least crystallite size (5.5 nm) was observed for the sample CZVP while the highest (23.8 nm) was observed for the sample CZCA. Cation distribution was proposed based on calculated and observed intensity ratios of selected planes from X ray diffraction data. All structural parameters were presented using experimental lattice constant and oxygen positional parameter, and they correlated with FT-IR results. Magnetic measurements were carried out using vibrating sample magnetometer at room temperature to obtain the characteristic parameters such as saturation magnetization, coercivity, remanence, squareness ratio and Bohr magnetons. Among all, the sample synthesized via citric acid autocombustion method displayed a remarkably higher magnetization of 53 emu/g and the remaining two samples displayed low magnetization values owing to their smaller crystallite sizes.
Dysprosium doped strontium silicate phosphor namely (Sr2SiO4:Dy3+) was prepared by low-temperature solution combustion method using urea (CO(NH2)2) as a fuel. The material was characterized by powder X-ray diffraction (XRD), FT-IR, SEM and EDX. The average crystallite sizes was calculated by Scherer formula. Thermoluminescence study was carried out for the phosphor which showed single glow curve. The kinetic parameter were calculated by using Chen’s glow curve method. Photoluminescence spectra revealed strong transition at 473 nm (blue), 571 nm (yellow) and weak transition at 645 nm (red). These peaks were assigned to transition 4F9/2 →6H15/2, 13/2, 11/2. CIE graph of Sr2SiO4:Dy3+ phosphor is suitable for the generation of white light emission.
W. Christopher Immanuel, S. Paul Mary Deborrah, S.S.R. Inbanathan and D. Nithyaa Sree
Polycrystalline chalcogenide semiconductors play a vital role in solar cell applications due to their outstanding electrical and optical properties. Among the chalcogenide semi-conductors, CdZnS is one kind of such important material for applications in various modern solid state devices such as solar cells, light emitting diode, detector etc. Due to their applications in numerous electro-optic devices, group II-VI semiconductors have been studied extensively. In recent years, major attention has been given to the study of electrical and optical properties of CdZnS thin films. In this work, Cd1−xZnxS thin films were prepared by chemical bath deposition technique. Phase purity and surface morphology properties were analyzed using field emission scanning electron microscope (FE-SEM) and X-ray diffraction (XRD) studies. Chemical composition was studied using energy dispersive spectrophotometry (EDS). Optical band gap property was investigated using UV-Spectroscopy. Electrical conductivity studies were performed by two probe method and thermoelectric power setup (TEP) to determine the type of the material. This work reports the effect of Zn on structural, electrical, microstructural and optical properties of these films.
Layered magnetic heterostructures are very promising candidates in spintronics in which the influences of interfaces, surfaces and defects play a crucial role. X-ray photoelectron spectroscopy (XPS) study has been performed for studying in detail the chemical state and electronic structure of Co2FeAl (CFA) Heusler alloy interfaced with Si substrates. XPS survey scan spectra have clearly shown the presence of Fe, Co and Al signal along with the signal due to Si. The presence of Co, Fe and Al signal confirms the formation of CFA alloy phase. Our XPS results support our previous study  on CFA/Si structure in determining the magnetic and transport properties across the interface.
Dmitrijs Goreļikovs, Margarita Urbaha, Dmitry Nedelko and Jonas Stankunas
Electronic Chart Display and Information Systems (ECDIS), which are used on vessels and can replace paper charts, allow to obtain and display on electronic charts information from basic and additional data sources. For the certified use of ECDIS instead of paper charts, it is necessary to ensure constant updating of Electronic Navigation Chart (ENC) data provided to vessels for use. The known visual and satellite observation systems intended for cartographic information update are costly, have low accuracy and do not allow to quickly update navigational charts in real-time mode. The stand-alone use of remotely piloted aircraft (RPA) will make it possible not only to substantially reduce costs and increase the accuracy of monitoring, but also to provide information in real-time mode.
Juris Maklakovs, Jevgēnijs Tereščenko and Vladimirs Šestakovs
In the field of security in transport distinguish risks related to flight safety and aviation security. Safety of flights is ensured through the reliability of aviation equipment and the qualification of the personnel who services and operates it, aviation security is a condition of protection from illegal interference in its activity. Risk management in civil aviation in the field of security is a relatively new direction of activity. Deep research in this area began only at the beginning of the XXI century. It is quite difficult to use the existing experience of risk management, accumulated in other spheres, as civil aviation has significant features. Various methods and schemes can be used to assess risks. The article discusses various options for predicting risks using the “event tree” and “risk factor tree” methods.
Andrii Grekhov, Vasil Kondratiuk and Svitlana Ilnitska
Original models of RPAS communication channels based on IEEE 802.11b Standard, including both Base Station transmission within the Radio Line of Sight, and through the satellite using Beyond Radio Line of Sight, were built. Dependencies of the Bit Error Rate on the Signal-Noise Ratio for different payload data rates were obtained. Transponder nonlinearity and Base Station antenna diameter impact were analysed.
The target of analyse was to determine the exposure levels to the staff on the vessel and ensure adequate measures are in place to minimize the exposure when necessary. Noise levels through the vessel will be compared to the noise code detailed in section 2 of this report. The measurement data results obtained at this survey will be analysed against the codes, as shown below. In addition, the measurement result table has the readings from 2007 during sea trials at the shipyard, Brodogradilište d.o.o. – Split. The analyse is to measure the exposure levels, through the accommodation and machinery spaces to determine the risk to staff working in these areas as well as making recommendations that could reduce the exposure levels.
The article describes the impact of the gas turbine engine low-pressure turbine blade shroud shelf on the blade profile stress position. Attention is focused directly on the impact of the location of the gravity centre of the shroud shelf on blade stress distribution at the three most critical points of the profile. The paper describes the details of the calculation and the required expressions provided, as well as the results of the calculation example with clear graphical dependencies.
Tomasz Kotwica, Jaroslaw Domaradzki, Damian Wojcieszak, Andrzej Sikora, Malgorzata Kot and Dieter Schmeisser
The paper presents results of investigations on surface properties of transparent semiconducting thin films based on (Ti-Cu)oxide system prepared using multi-magnetron sputtering system. The thin films were prepared using two programmed profiles of pulse width modulation coefficient, so called V- and U-shape profiles. The applied powering profiles allowed fabrication of thin films with gradient distribution of Ti and Cu elements over the thickness of deposited layers. Optical investigations allowed determination of transparency of prepared films that reached up to 60 % in the visible part of optical radiation, which makes them attractive for the transparent electronics domain. Surface properties investigations showed that the surface of mixed (Ti-Cu)oxides was sensitive to adsorption, in particular to carbon dioxide and water vapor. Soft etching with argon ions resulted in surface cleaning from residuals, however, deoxidation of Cu-oxide components was also observed.