An inorganic coordination complex of single crystal containing sodium and aluminum (SA) was grown at room temperature by slow evaporation technique. The crystal was characterized using single crystal X-ray diffraction (XRD), FT-IR, UV-Vis, SHG, SEM, EDX and TG/DTA analyses. The size of the grown crystal was around 17 mm × 15 mm × 5 mm. Both optical and SEM photographs confirmed that the crystal is transparent with smooth surface. The XRD data showed that the crystal belongs to the BCC crystal structure. The crystal shows excellent transparency in the entire region of visible light (cut-off value is 339 cm−1). The dielectric constant as well as dielectric loss of the sample was calculated by varying frequencies at different temperatures and the presence of low dielectric loss proved that this crystal can be used for the NLO application.
Božana Čolović, Danilo Kisić, Bojan Jokanović, Zlatko Rakočević, Ilija Nasov, Anka Trajkovska Petkoska and Vukoman Jokanović
Thin films of titanium oxides, titanium oxynitrides and titanium nitrides were deposited on glass substrates by the methods of direct current (DC) and pulsed magnetron sputtering and cathodic arc evaporation. Phase analysis of the deposited films by X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FT-IR) showed the presence of phases with various Ti oxidative states, which indicated a high concentration of oxygen vacancies. The films morphology was investigated by scanning electron microscopy (SEM). Investigations of the films wettability, either with water or ethylene glycol, showed that it depends directly on the concentration of oxygen vacancies. The wettability mechanism was particularly discussed.
Nanostructured CdO thin films have been prepared on glass substrates by spray pyrolysis technique using perfume atomizer from fresh and aged (1, 2, 3 and 4 days) precursor solutions. XRD studies confirm that all the films exhibit cubic crystal structure with a (1 1 1) preferential orientation. The preferential orientation factor f(1 1 1) increases with an increase in aging the period of precursor solution. The 2θ value of the (1 1 1) plane shifts towards lower Bragg angles with aging inferring an expansion in the lattice volume of the aged films. Increased crystallite size is observed for the 3-days aged film for which minimum strain and dislocation density values are obtained. Optical transparency increases with an increase in aging period of the precursor solution and the optical band gap exhibits a red shift from 2.48 eV to 2.32 eV. Minimum resistivity of 0.78 × 10−2 Ω·cm is observed for the CdO film prepared from 3-days aged solution. The obtained results infer that the CdO film prepared from 3-days aged solution exhibits better physical properties than the others.
Jaydeep Dogney, Payal Bhargava and Arvind Kumar Shrimali
To improve the reputation and customer loyalty, a benchmarking analysis is being carried out, which influences the perception of the service quality for banks. With the expansion of competitive interactions, the results can serve as a strategic tool to gain competitive advantage and customer satisfaction. Banks reveal the expectations and expectations of customers regarding the quality of selected services. The process creates and expands its reputation and builds customer loyalty. This research aims to compare the perception of the quality of four leading banks with logical comparisons.
The research of railway track surfaces is aimed at improving the quality of railway infrastructure and providing the chance of improving the safety of driving. Therefore, it is advisable to constantly monitor track surface, but the research itself is not innovative because it is based on a known procedure. The crucial element are the techniques that allow to delve into the sources of problems. The aim of the article is to use the selected instruments of quality management to analyze the causes of track twist at high (180 km/h) speed of driving. The analysis of the causes of track twist was done on the basis of results from the measurement of one kilometer track section of the Krakow Glowny - Medyka route, which was made by using the TEC measuring device in April 2018. It was inferred that it is impossible to reach 180 km/h without track twist. In order to identify the causes of track twist it was proposed to use the selected sequence of quality management instruments, i.e.: brainstorming, Ishikawa diagram and the 5Why method. The identified causes of track twist include the abrasion of rail, scratches and exploitation point. The analysis and conclusions drawn from it may be useful in the analysis of other problems in railway transport as well as production and service industries.
Pure CdO nanopowder and CdO-Fe3O4 nanocomposite were synthesized by a cost effective chemical method, and the samples were characterized by XRD, SEM, TEM, FT-IR, UV-Vis-NIR and PL. Also, magnetic and photocatalytic properties of the synthesized samples were studied. XRD patterns of the composite confirm the presence of diffraction peaks related to both CdO and Fe3O4. EDX spectrum confirms the presence of the elements Cd, O and Fe in the composite. Peaks related to Cd–O and Fe–O bonds were observed respectively at 688 cm−1 and 592 cm−1 in the FT-IR spectrum. The paramagnetic behavior of pure CdO becomes ferromagnetic when coupled with Fe3O4. The composite exhibited a high photodegradation efficiency of 92.85 % against the degradation of methylene blue dye under visible light radiation.
The research is focused on the study of the temperature dependence of the internal damping of selected magnesium alloys with different contents of aluminium - AZ31 and AZ61. These alloys are currently widely used in various types of industry, mainly in the automotive industry. It belongs to a group of materials called HIDAMETS because they have excellent damping properties. The internal damping of the samples was measured on a unique ultrasonic device constructed at Žilina University in Žilina. Specimens were measured at baseline in the temperature range from 25 °C to 400 °C. Changes in internal damping caused by varying aluminium contents in investigated alloys were noted. As the aluminium content increases, maximum internal damping is achieved due to the formation, growth and subsequent dissolution of the continuous precipitate in the microstructure.
The article describes 10 known programmes of practical flight training in military aviation – specialization: Multi-Mission Tactical Jet Pilot, which is the highest level of military pilot training in all types of military and civil aviation – comparable only to the level of training and experience of the pilot-instructor of the Military Aviation School. The presented comparison was developed on the basis of literature research from the point of view of, among others, an aircraft operation engineer and a pilot-instructor.
The objective of the paper is to analyze the cooperation in craft beer manufacturing in Poland and to identify the specificity of this phenomenon from the perspective of enterprise management. The sales of craft beers in Poland are growing rapidly. Craft beers have about a 0.5% share in the total beer sales value in Poland. The popular practice in the industry is contract brewing. It is an interesting phenomenon in the field of cooperation of enterprises which can be classified and analyzed as a form of: economic cooperation (generally), production cooperation, outsourcing, network and virtual organization and also coopetition. It is a specific business model. Contract brewing is a complex problem the specificity of which emerges on several levels. Firstly, there is a special way to emerge in the market of craft beers, even while not possessing significant funds by the entrepreneur. Secondly, it is a form of cooperation in the field of production which unites efforts on the side of both the customer and the contractor since it is not limited to normal outsourcing of production to an external entity but involves physical production capacity of the contractor and technological know-how of both cooperation parties. Thirdly, it is firmly embedded in human relationships. Fourthly, it can generate coopetitive relations since the brewery accepting the order may conduct its own activity related to production and sales of beer under its own brand.