Nanosized NaA zeolite was successfully synthesized by hydrothermal method using tetraethyl orthosilicate (TEOS) and aluminum isopropoxide (AIP) as the main raw materials. The surface modification of NaA zeolite was carried out by silane coupling agent 3-aminopropyltriethoxysilane (KH-550). The effects of silane coupling agent dosage, reaction temperature, reaction time, hydrolysis time and pH value on grafting rate of NaA zeolite were investigated in detail. The zeolites were characterized by XRD, SEM-EDS, FT-IR and TG-DTA. The results showed that the surface of NaA zeolite was modified successfully by KH-550. The optimal modification conditions obtained were as follows: the dosage of coupling agent in 95 % ethanol – 1.6 %, reaction temperature − 70 °C, reaction time – 2 h, hydrolysis time – 20 min, and pH value – 3.5. Under these conditions, the grafting rate of modified NaA zeolite was 3.95 %.
P. Venkateswara Rao, G. Naga Raju, P. Syam Prasad, T. Satyanarayana, L. Srinivasa Rao, F. Goumeidane, M. Iezid, W. Marltan, G. Sahaya Baskaran and N. Veeraiah
PbO-ZnF2-P2O5 glasses doped with different mol% (0.1 to 1.0) of MoO3 have been prepared. Dielectric properties ∊′(ω), tanδ, σAC, of the synthesized samples were calculated from frequency measurements versus temperature. Space charge polarization was used to analyze the temperature and frequency dispersions of dielectric constant ∊′(ω) and dielectric loss tanδ. Quantum mechanical tunneling model was employed to explain the origin of AC conductivity. The AC conductivity exhibited an increasing trend with increasing concentration of MoO3 (up to 0.2 mol%) but the activation energy for conduction decreased. The plots of AC conductivity revealed that the relaxation dynamics depends on MoO3 dopant concentration.
Activated carbons and carbon nanotube were synthesized with chemical and microwave processes of olive leaf in media with and without ultrasonic waves, and chemical vapor deposition method, respectively. The samples were characterized by x-ray diffraction, calorimetry, Brunauer, Emmett and Teller method, scanning electron microscopy/energy-dispersive X-ray, and zetasizer nano S90 instruments. The activated carbon synthesized in the ultrasonic bath had a higher surface area. The hydrogen adsorption capacity of carbon structures including activated carbons and carbon nanotube was measured as a function of pressure at 77 K. The hydrogen storage capacity of the carbon nanotube is 300% and 265% higher than the hydrogen storage capacity of activated carbons synthesized in medium without and with ultrasonic waves, respectively. Results showed the correlation between hydrogen storage capacity and specific surface area. The highest H2 storage value was obtained with carbon nanotube at 77 K. As a result, activated carbon and carbon nanotube can be used in hydrogen storage and therefore, the olive leaf can be converted into a high added value product in the energy field.
M. Suresh Kumar, K. Rajesh, G.V. Vijayaraghavan and S. Krishnan
Good quality diglycine perchlorate (DGPCL) single crystals were grown by slow evaporation solution growth method using the combination of glycine and perchloric acid in the ratio of 2:1. Single crystal X-ray diffraction and mechanical characterization of the grown single crystals of diglycine perchlorate were analyzed in this article. Lattice parameters, space group and crytal system were found from single crystal X-ray diffraction analysis. All the cell parameters and space group are in a good agreement with the reported values. Mechanical properties, such as Vicker’s microhardness number, work hardening index, standard hardness value, yield strength, fracture toughness, brittleness index and elastic stiffness constant values, were determined using Vicker’s microhardness tester.
Surendra Singh, Anshuman Sahai, S.C. Katyal and Navendu Goswami
We have synthesized zinc-copper ferrite (ZCFO) employing exploding wire technique (EWT). The X-ray diffraction (XRD) data confirm the formation of single phase spinel ZCFO, which is in good agreement with Fourier transform infrared spectroscopy (FT-IR), UV-Vis, and Raman spectroscopic analyses. It is also clearly seen in the SEM micrographs that the grains in ZCFO ferrite are very rough, which allows adsorption of gas like oxygen and therefore, the material can behave as active sensing surface. The size range of the grains in prepared sample is of 200 nm to 500 nm. The FT-IR spectrum of the nanocomposite consists of two broad bands, one at 580.4 cm−1 due to M–O stretching mode at the tetrahedral site and the other at 400.7 cm−1 due to M–O stretching mode at the octahedral site. The nanoparticles show a UV-Vis absorption band in the wavelength region of 400 nm to 700 nm. The energy band gap for the prepared nanomaterial was estimated to be 3.16 eV. Thus, the ferrite nanocomposite prepared by EWT is optically active. According to present literature, Raman spectroscopy study on zinc-copper ferrite system has not been reported till date. By suitable attributing various Raman modes, we have further confirmed the formation of ZCFO nanophase through the present novel approach.
B. Punithaveni, K. Thilagavathy, N. Muthukumarasamy, D. Nithyaprakash and M. Saravanabhavan
New organic single crystals of 2-amino-6-methylpyridinium 2-hydroxybenzoate (2A6M2H) were grown by slow evaporation solution growth technique at room temperature. The grown crystal structure was studied using single crystal XRD. Crystalline nature and phases were confirmed by powder XRD analysis. FT-IR study was used to identify the functional groups present in the compound. UV-Vis study revealed that the lower cut off wavelength of the crystal is at 350 nm. The dielectric studies indicated the low value of dielectric loss at high frequency. Mechanical properties of the crystals were studied using Vickers microhardness test. The Z-Scan studies were conducted for the crystal using He–Ne laser.
Single crystal of glycine hydroflruoride (GHF) was grown from aqueous solution by slow evaporation technique. The structure of the grown crystal was tested and analyzed through X-ray powder diffraction. The functional groups have been identified from the FT-IR spectra. Slabs cut normal to the b-axis from the grown crystal were subjected to incident radiation with a wavelength range of 200 nm to 800 nm to investigate the transmittance and reflectance spectra. Linear optical parameters such as extinction coefficient k, refractive index n and both the real and imaginary parts: ∊real and ∊im of the dielectric permittivity were calculated as functions of the incident photon energy. The dispersion of the refractive index was fitted in terms of Cauchy formula and Wemple-DiDomenico single oscillator model. GHF crystals exhibited indirect optical interband transition and the optical energy gap Eg was determined by using Tauc plot. The indirect band gaps at elevated temperatures were determined and their temperature dependence was estimated. Optical band gap Eg values were found to decrease with an increase in crystal temperature; however, the band tail width exhibited opposite behavior. The nonlinear optical potential was examined by the second harmonic generation (SHG) test.
İsmet Kaya, Feyza Kolcu, Sabriye Satilmiş and Zeynep Yazicioglu
A series of polyimines, bearing phenolic groups were successfully synthesized in aqueous alkaline solution via chemical oxidative polycondensation. Polymeric Schiff bases were synthesized by condensation of 2,4-dihydroxybenzaldehyde and 3-hydroxy-4-metoxybenzaldehyde with 2-aminophenol and 3-aminophenol. The molecular structures of the synthesized Schiff bases and their corresponding polymers were studied by FT-IR, UV-Vis, 1H-NMR and 13C-NMR spectroscopic methods. Thermal stability of the imine polymers was evidenced by their initial degradation temperatures found in the range of 170 °C to 271 °C without any sign of melting. The results of UV-Vis and cyclic voltammetry (CV) measurements were coherent with the optical Eg and the electrochemical E′g band gaps of the polyimines which were lower than those of their corresponding Schiff bases. Fluorescence spectral analysis of P4 (Schiff base polymer P4 derived from 3-aminophenol and 3-hydroxy-4-methoxybenzaldehyde) revealed a bicolor emission with blue and green light. Electrical conductivity of the synthesized imine polymers was measured by four-point probe technique. P4 showed the highest electrical conductivity as a result of iodine vapor contact time. Morphology characterization of the synthesized polyimines was carried out using a scanning electron microscope SEM at different magnifications. The study revealed that P4 is a promising candidate for both blue and green light emitters which could be used in the production of photovoltaic materials and solar cells.
S. Reena Devi, S. Suresh, S. Kalaiyarasi, M. Nizammohideen and R. Mohan Kumar
A novel 4-methylpyridinium 3-nitrophthalate (4MP3NP) was synthesized and the crystals were grown by using slow evaporation method. The structural data of the grown crystal was collected by single crystal X-ray diffraction. It revealed that the 4MP3NP crystal belongs to triclinic crystal system with a space group P1. Structure of the synthesized compound was established using SHELXL 97 program package. The crystalline nature and composition of the grown crystal was established using high resolution X-ray diffraction and FT-IR analyses. UV-Vis transmittance and photoluminescence studies revealed the optical transmission window and electronic transition mechanism of ions, respectively. The laser damage threshold of the grown crystal was estimated by Nd:YAG laser and these results were mutually related to specific heat capacity of the grown crystal. The third-order nonlinear optical susceptibility of the grown crystal was studied by Z-scan technique.
In this work, multi-walled carbon nanotubes (MWCNTs) with significantly different mean diameters were produced by catalytic CVD over Ni and Co-based supported catalysts. Our results indicate that Ni nanoparticles in the Ni/MgO catalyst are responsible for controlling the inner diameters of the carbon nanotubes. Contrary, Co nanoparticles in the Co/MgO catalyst control the outer diameters of MWCNTs. The “base-growth” mechanism and smaller diameters of the MWCNTs grown on the Ni/MgO catalyst are associated with a strong metal-support interaction (SMSI) resulting from NixMg1−xO mixed oxide formation. The concept of the weak metal-support interaction (WMSI) between Co nanoparticles and MgO for the Co/MgO catalyst confirms the “tip-growth” mechanism of the MWCNTs.