Nanostructured CdO thin films have been prepared on glass substrates by spray pyrolysis technique using perfume atomizer from fresh and aged (1, 2, 3 and 4 days) precursor solutions. XRD studies confirm that all the films exhibit cubic crystal structure with a (1 1 1) preferential orientation. The preferential orientation factor f(1 1 1) increases with an increase in aging the period of precursor solution. The 2θ value of the (1 1 1) plane shifts towards lower Bragg angles with aging inferring an expansion in the lattice volume of the aged films. Increased crystallite size is observed for the 3-days aged film for which minimum strain and dislocation density values are obtained. Optical transparency increases with an increase in aging period of the precursor solution and the optical band gap exhibits a red shift from 2.48 eV to 2.32 eV. Minimum resistivity of 0.78 × 10−2 Ω·cm is observed for the CdO film prepared from 3-days aged solution. The obtained results infer that the CdO film prepared from 3-days aged solution exhibits better physical properties than the others.
Jaydeep Dogney, Payal Bhargava and Arvind Kumar Shrimali
To improve the reputation and customer loyalty, a benchmarking analysis is being carried out, which influences the perception of the service quality for banks. With the expansion of competitive interactions, the results can serve as a strategic tool to gain competitive advantage and customer satisfaction. Banks reveal the expectations and expectations of customers regarding the quality of selected services. The process creates and expands its reputation and builds customer loyalty. This research aims to compare the perception of the quality of four leading banks with logical comparisons.
The research of railway track surfaces is aimed at improving the quality of railway infrastructure and providing the chance of improving the safety of driving. Therefore, it is advisable to constantly monitor track surface, but the research itself is not innovative because it is based on a known procedure. The crucial element are the techniques that allow to delve into the sources of problems. The aim of the article is to use the selected instruments of quality management to analyze the causes of track twist at high (180 km/h) speed of driving. The analysis of the causes of track twist was done on the basis of results from the measurement of one kilometer track section of the Krakow Glowny - Medyka route, which was made by using the TEC measuring device in April 2018. It was inferred that it is impossible to reach 180 km/h without track twist. In order to identify the causes of track twist it was proposed to use the selected sequence of quality management instruments, i.e.: brainstorming, Ishikawa diagram and the 5Why method. The identified causes of track twist include the abrasion of rail, scratches and exploitation point. The analysis and conclusions drawn from it may be useful in the analysis of other problems in railway transport as well as production and service industries.
Pure CdO nanopowder and CdO-Fe3O4 nanocomposite were synthesized by a cost effective chemical method, and the samples were characterized by XRD, SEM, TEM, FT-IR, UV-Vis-NIR and PL. Also, magnetic and photocatalytic properties of the synthesized samples were studied. XRD patterns of the composite confirm the presence of diffraction peaks related to both CdO and Fe3O4. EDX spectrum confirms the presence of the elements Cd, O and Fe in the composite. Peaks related to Cd–O and Fe–O bonds were observed respectively at 688 cm−1 and 592 cm−1 in the FT-IR spectrum. The paramagnetic behavior of pure CdO becomes ferromagnetic when coupled with Fe3O4. The composite exhibited a high photodegradation efficiency of 92.85 % against the degradation of methylene blue dye under visible light radiation.
The research is focused on the study of the temperature dependence of the internal damping of selected magnesium alloys with different contents of aluminium - AZ31 and AZ61. These alloys are currently widely used in various types of industry, mainly in the automotive industry. It belongs to a group of materials called HIDAMETS because they have excellent damping properties. The internal damping of the samples was measured on a unique ultrasonic device constructed at Žilina University in Žilina. Specimens were measured at baseline in the temperature range from 25 °C to 400 °C. Changes in internal damping caused by varying aluminium contents in investigated alloys were noted. As the aluminium content increases, maximum internal damping is achieved due to the formation, growth and subsequent dissolution of the continuous precipitate in the microstructure.
The article describes 10 known programmes of practical flight training in military aviation – specialization: Multi-Mission Tactical Jet Pilot, which is the highest level of military pilot training in all types of military and civil aviation – comparable only to the level of training and experience of the pilot-instructor of the Military Aviation School. The presented comparison was developed on the basis of literature research from the point of view of, among others, an aircraft operation engineer and a pilot-instructor.
The objective of the paper is to analyze the cooperation in craft beer manufacturing in Poland and to identify the specificity of this phenomenon from the perspective of enterprise management. The sales of craft beers in Poland are growing rapidly. Craft beers have about a 0.5% share in the total beer sales value in Poland. The popular practice in the industry is contract brewing. It is an interesting phenomenon in the field of cooperation of enterprises which can be classified and analyzed as a form of: economic cooperation (generally), production cooperation, outsourcing, network and virtual organization and also coopetition. It is a specific business model. Contract brewing is a complex problem the specificity of which emerges on several levels. Firstly, there is a special way to emerge in the market of craft beers, even while not possessing significant funds by the entrepreneur. Secondly, it is a form of cooperation in the field of production which unites efforts on the side of both the customer and the contractor since it is not limited to normal outsourcing of production to an external entity but involves physical production capacity of the contractor and technological know-how of both cooperation parties. Thirdly, it is firmly embedded in human relationships. Fourthly, it can generate coopetitive relations since the brewery accepting the order may conduct its own activity related to production and sales of beer under its own brand.
In this study, CdZnO films prepared at different ratios of dopants (CdO:ZnO = 5:5, CdO:ZnO = 6:4, and CdO:ZnO = 8:2) were coated on glass surface by using the sol-gel spin coating technique. After this process, surface structure and optical properties of the CdZnO films was investigated by atomic force microscopy (AFM) and UV-Vis spectroscopy. The surface structure of the CdZnO films depended on the content of ZnO and CdO in the films. Low percentage of CdO films were very similar to the ZnO film but higher amount of CdO resuted in granular structures together with pure structure of ZnO in the films. Eg values of produced CdZnOs depended on the additions of CdO and ZnO. The obtained Eg values of the produced CdO:ZnO = 5:5 (S3), CdO:ZnO = 6:4 (S4), and CdO:ZnO = 8:2 (S5) films are 2.5 eV, 2.49 eV, and 2.4 eV, respectively.
Nanocomposite silica thin films made using the sol-gel method were studied. The nano-silica films were prepared using a mixture of tetraethyl orthosilicate (TEOS), deionized water, ethanol, and ammonia solution. To control the growth of the particles inside the film, the nanocomposite silica film was prepared using a mixture of the nano-silica sol and the silica sol. The change in the particle size with the heat treatment temperature ranging from 450 °C to 1100 °C was investigated. X-ray diffraction (XRD), atomic force microscopy (AFM), scanning electron microscopy (SEM), NKD (refractive index-N, extinction coefficient-K, and thickness-D) and ultraviolet-visible (UV-Vis) spectrophotometry were used for characterization purposes. The XRD studies showed that the nano-silica thin films were amorphous at all annealing temperatures except for 1100 °C. The_-cristobalite crystal structure formed at the annealing temperature of 1100 °C. Optical parameters, such as refractive indices and extinction coefficients, were obtained using the NKD analyzer with respect to the annealing temperature of the films. The activation energy and enthalpy of the nanocomposite silica film were evaluated as 22.3 kJ/mol and 14.7 kJ/mol, respectively. The cut-off wavelength values were calculated by means of extrapolation of the absorbance spectra estimated using the UV-Vis spectroscopy measurements. A red shift in the absorption threshold of the nanocomposite silica films indicated that the size of the silica nanoparticles increased with an increase of the annealing temperatures from 450 °C to 900 °C, and this confirms the quantum confinement effect in the nanoparticles.
Structural, electronic, intrinsic magnetic, anisotropic elastic properties, sound velocities and Debye temperature of Fe1−xMnx B (x = 0, 0.25, 0.5, 0.75, 1) transition metal monoborides have been studied by first-principles calculations within the method of virtual crystal approximation (VCA) based on density-functional theory (DFT) through generalized gradient approximation (GGA). The average magnetic moment per cell increased with increasing of Mn content, which could be associated with the relationship between the composition and magnetic properties. The observed magnetic behavior of Fe1−xMnx B compounds can be explained by Stoner model. Lattice parameters and Debye temperature agree well with the experimental values. Furthermore, we have plotted three-dimensional (3D) surfaces and planar contours of the directional dependent Young and bulk moduli of the compounds on several crystallographic planes, to reveal their elastic anisotropy versus Mn content (x) in Fe1−xMnx B.