This article presents adhesive shearing test methods, focusing especially on the ASTM D5656 method. These methods will be briefly characterized and compared. The most important concerns about the D5656 method are described. With the use of ASTM D1002 and D5656 methods, the influence of adherend surface preparation on shearing properties of the bond is evaluated. Compared to sandblasting only, sandblasting followed by the FPL process (sulfochromate etching of aluminum) increased shear strength of joints by 35 % for ASTM D1002 tests and by 48% for D5656 tests. Comparing these two methods, shear strength obtained in D5656 tests is about two times higher than in D1002 tests. The cause for this phenomena is much larger adherend thickness in the D5656 method, which provides the coupons with increased stiffness. Shear modulus, calculated with 3 different calculation methods, showed differences in obtained results, which points to necessary actualization of D5656 standard.
Publication contains a description of the preparation and the implementation of a test flight of a stratospheric balloon with a mounted camera GoPro Hero3. Description includes: used equipment, its parameters, role in the success of the mission and the difficulties and limitations that the project team encountered during the preparation and implementation of the flight. The mission was attended by a team of six engineers and scientists from the Remote Sensing Division, who were also involved in the implementation of the HESOFF project. One of the main goals of the HESOFF project was to obtain aerial images on the Krotoszyńska Plate (woj. wielkopolskie) using the Unmanned Aerial Vehicle (UAV) and to carry out remote monitoring of oak stands. The primary goal of an experimental balloon flight was to check the technical operational capability and gain experience in planning and implementing this type of project. During the balloon raising, the video material was acquired in the form of a recording, which later was analyzed. On the basis of the collected information, the conclusions regarding the possibility of implementing a long endurance flight in the stratosphere, illustrating (using a multisensor platform) research surfaces of the HESOFF project were presented. The stages of implementation of the presented mission were divided into following parts: preparation of the flight with the completion of equipment and necessary documents (flight permission), proper flight realization, understood as the release of the balloon and identification of the place where the equipment landed, as well as analysis and presentation of the results.
Presented paper concentrate on problems connected with FMEA method usage in industrial enterprise. There is in the paper a description of the basic rules of FMEA method and competition between FMEA analysis and gap analysis. The analysis of defects has been done to find recommendations how to eliminate or restrain them. On the basis of conducted research we found that selection of staff to the team is very important factor in the FMEA analysis undertaking process. The staff should have appropriate level of knowledge about FMEA method methodology and other tools which are indispensable in the process of implementing this method within the company.
This paper is a review of testing methods dedicated for sandwich type composite structures with honeycomb core. First, information about the composition of sandwich materials structures, their properties, types of core materials and applications in the industry is presented. Mechanical properties were compared in the case of different types of the core material. Later, tests methods needed to describe properties of those materials and normalization organizations which create them were mentioned. The testing methods were divided into two groups: mechanical and physicochemical tests. Mechanical properties are: compressive strength (two types of test), edge compressive strength, shear strength (in two directions) and tension strength (two types of test). Physicochemical properties are: material density, water migration, water absorption and thermal conductivity. Testing methods were described according to American Society for Testing and Materials (ASTM) standards. This article is based on professional literature and the author’s experience.
Crystallization of γ-glycine in the presence of selected concentration (9 g/mL) of tailor-made additive magnesium sulfate heptahydrate salt (MgSO4·7H2O) has been studied at ambient temperature by adopting slow solvent evaporation procedure. The morphological modifications of glycine crystals grown from pure aqueous solutions of glycine and from glycine solutions containing magnesium species in the amount of 0.1 g/mL to 16 g/mL have been investigated thoroughly. The crystalline nature and phase identification of the crystalline material were confirmed by X-ray powder diffraction and SXRD studies. NMR studies revealed the information about the molecular conformation in solution, phase changes, functional groups and chemical environment. FT-IR spectra revealed distinct difference between α and γ-glycine polymorphs in the region around 880 cm−1 to 930 cm−1. The grown γ-glycine crystal had a lower cut-off value at 200 nm and the bandgap value evaluated from the Tauc plot was found to be 5.83 eV. The marked differences between α and γ-polymorphs of glycine were also revealed by DSC thermograms. The mechanical strength of the γ-glycine crystal was studied with the help of Vickers microhardness instrument. Kurtz-powder NLO study proved the generation of second harmonics (i.e. green light emission) in the grown γ-glycine crystal and its efficiency was calculated as 1.44 times better than that of the reference material potassium dihydrogen phosphate.
The paper presents simulation method and results of calculations determining behavior of helicopter and landing site loads which are generated during phase of the helicopter take-off and landing. For helicopter with whirling rotor standing on ground or touching it, the loads of landing gear depend on the parameters of helicopter movement, occurrence of wind gusts and control of pitch angle of the rotor blades. The considered model of helicopter consists of the fuselage and main transmission treated as rigid bodies connected with elastic elements. The fuselage is supported by landing gear modeled by units of spring and damping elements. The rotor blades are modeled as elastic axes with sets of lumped masses of blade segments distributed along them. The Runge-Kutta method was used to solve the equations of motion of the helicopter model. According to the Galerkin method, it was assumed that the parameters of the elastic blade motion can be treated as a combination of its bending and torsion eigen modes. For calculations, data of a hypothetical light helicopter were applied. Simulation results were presented for the cases of landing helicopter touching ground with different vertical speed and for phase of take-off including influence of rotor speed changes, wind gust and control of blade pitch. The simulation method may help to define the limits of helicopter safe operation on the landing surfaces.
Omer Kaygili, Niyazi Bulut, Tankut Ates, Ismail Ercan, Suleyman Koytepe, Turgay Seckin, Cengiz Tatar, Bayram Gunduz and Hanifi Kebiroglu
In the present study, the dopant effect of Zn on the crystal structure, thermal properties and morphology of magnesium aluminate (MgAl2O4) spinel (MAS) structure was investigated. A pure and two Zn-containing MASs (e.g. MgAl1.93Zn0.07O4 and MgAl1.86Zn0.14O4) were synthesized for this purpose via a wet chemical method, and the as-prepared samples were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, differential thermal analysis (DTA), thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) spectroscopy techniques. It was found that the crystal structure, thermal properties and morphology of the MAS system change with the increase in the amount of Zn. MgO phase formation was observed. The values of the lattice parameter, unit cell volume and crystallite size increased, and the crystallinity percentage decreased. The morphology was also affected by adding of Zn.
Madiha Sarfraz, Nasar Ahmed, Khizar-ul-Haq, Shabnam Shahida and M. A. Khan
Transition metals, such as chromium (Cr) and manganese (Mn) doped zinc oxide (ZnO) magnetic nanoparticles, were synthesized via sole gel auto-combustion method. The prepared magnetic (Zn1−(x+y)MnxCryO, where x, y = 0, 0.02, 0.075) nanoparticles were calcined in an oven at 6000 °C for 2 hours. The morphologies of the nanoparticles were investigated using different techniques. X-ray diffraction (XRD) analysis revealed that the hexagonal wurtzite structure of the synthesized nanoparticles was unaffected by doping concentration. The crystallite size measured by Scherrer formula was in the range of 32 nm to 38 nm at different doping concentrations. Nanosized particles with well-defined boundaries were observed using a field emission scanning electron microscopy (FE-SEM). Fourier transform infrared (FT-IR) spectra showed a wide absorption band around 1589 cm−1 in all the samples, corresponding to the stretching vibration of zinc and oxygen Zn–O bond. A blue shift in optical band gaps from 3.20 eV for ZnO to 3.08 eV for Zn0.85Mn0.075Cr0.075O nanoparticles was observed in diffuse reflectance spectra, which was attributed to the sp-d exchange interactions. The field-dependent magnetization M-H loops were measured using vibrating sample magnetometer (VSM). The VSM results revealed diamagnetic behavior of the ZnO nanoparticles which changed into ferromagnetic, depending on the doping concentration and particle size. The compositions of Zn, Cr, Mn and O in the prepared samples were confirmed by using the energy dispersive X-ray spectroscopy (EDX). Our results provided an interesting route to improve magnetic properties of ZnO nanoparticles, which may get significant attention for the fabrication of magnetic semiconductors.
In the present work, a new organic second order NLO material: L-isoleucinium p-toluenesulfonate monohydrate (LIPT) is synthesized and reported for the first time. The LIPT is crystallized in a non-centrosymmetric monoclinic space group P21. Structural and hydrogen bond nature of the compound is analyzed using single crystal X-ray diffraction studies. The crystal exhibits very good optical properties such as wide optical transparency in the region of 210 nm to 1100 nm and the ultraviolet wavelength emission (λ = 283 nm). The second harmonic generation efficiency is found to be 1.7 times the standard KDP. Good thermal, mechanical properties and low dielectric constant at high frequency range show that the material may be a potential candidate for optoelectronic applications.
In this communication, we report on Cu2SnS3 quantum dots synthesized by the solvothermal process using different solvents. The optical properties of the quantum dots are analyzed by UV-Vis-NIR and photoluminescence spectroscopy. The results suggest that Cu2SnS3 material has tunable energy bandgap and appropriate wavelength for fabrication of light emitting diodes and laser diodes as sources for fiber optic communication. They exhibit wide absorption in the near infrared range. Further morphological studies with the use of atomic force microscope confirm the surface topography and the existence of quantum dots. The observed characteristics prove the efficiency of Cu2SnS3 quantum dots for O-band wavelength detection used in fiber optic communication and solar cell applications.