Optical properties of Si single crystals with different orientations (1 0 0) and (1 1 1) were investigated using spectrophotometric measurements in a spectral range of 200 nm to 2500 nm. The data of optical absorption revealed an indirect allowed transition with energy gap of 1.1 ± 0.025 eV. An anomalous dispersion in refractive index. The normal dispersion of the refractive index was discussed according to Wemple-DiDomenico single oscillator model. The oscillator energy Eo, dispersion energy Ed, high frequency dielectric constant ∈∞, lattice dielectric constant ∈L and electronic polarizability αe were estimated. The real ∈1 and imaginary ∈2 parts of dielectric constant were also determined.
The Durmitor flysch complex represents a specific formation both in lithological and engineering geological sense. In the engineering geological sense this lithological formation is characterized by anisotropic and heterogeneous geotechnical properties, which depend on the dominant members within each individual package, as well as their spatial position.The Durmitor flysch complex consists of five superposition bed packages, which are mutually substantially different in their lithological, hydrogeological and geotechnical properties. For the first time in geological literature, this paper distinguishes five types of terrain construction within the Durmitor flysch complex. Contemporary geodynamic processes and their character within the flysch formation are defined. Particular emphasis is put on landslides, which represent a contemporary geodynamic phenomenon with certain specificities.
I. C. Okeyode, O. T. Olurin, S. A. Ganiyu and J. A. Olowofela
The study of the nature of distribution of natural radioelements in Ilesha and its environs with its geological structure has been studied using aeroradiometric data. Aeromagnetic data have also been subjected to three automated gradient techniques to delineate the sub-surface structure of the study area. From the study, it can be found that maximum values of “eU” (ppm) and “eTh” (ppm) fall within the branded gneiss, whereas the maximum value of K (%) falls within porphyritic granite regions. eTh had the highest radioactive content. The environmental dose rate of Ilesha was between 0.1817 and 3.9296 msv/yr. Although there were extreme values, but the mean dose rate was 0.522 ± 0.310 msv/yr (within acceptable safe limit of 1.0 msv/yr). eU/K, eU/eTh and eTh/K ratios were analysed for enrichment or depletion of radioisotopes. eU/eTh >1 showed uranium depletion, while eTh >2 showed eTh enrichment. The magnetic intensity values ranged from -79.41 to 140.93 nT. The horizontal gradient method (HGM) and analytic signal amplitude (ASA) revealed that depth to magnetic sources ranged from 0.478 to 4.112 km and 0.348 to 2.551 km, respectively, whereas local wavenumber (LWN) depth ranged from 0.478 to 5.48 km, which overestimated those compared using HGM and ASA functions. The apparent susceptibility ranged from -0.00325 to 0.00323 SI, showing that ferromagnetic and diamagnetic mineral ranges control apparent susceptibility in Ilesha.
A.K. Sharma, S.S. Potdar, M.A. Yewale, Deepak B. Shirgaonkar, K.S. Pakhare, B.M. Sargar, M.V. Rokade and U.M. Patil
Cadmium oxide (CdO) thin films were synthesized using chemical bath deposition (CBD) method from aqueous cadmium nitrate solution. The bath temperatures were maintained at room temperature (25 °C) and at higher temperature (80 °C). The structural studies revealed that the films showed mixed phases of CdO and Cd(OH)2 with hexagonal/monoclinic crystal structure. Annealing treatment removed the hydroxide phase and the films converted into pure CdO with cubic, face centered crystal structure. SEM micrographs of as-deposited films revealed nanowire-like morphology for room temperature deposited films while nanorod-like morphology for high temperature deposited films. However, cube-like morphology was observed after air annealing. Elemental composition was confirmed by EDAX analysis. Band gap energies of the as-deposited films varied over the range of 3 eV to 3.5 eV, whereas the annealed films showed band gap energy variation in the range of 2.2 eV to 2.4 eV. The annealed films were successfully investigated for NH3 sensing at different operating temperatures and at different gas concentrations. The room temperature synthesized film showed a response of 17.3 %, whereas high temperature synthesized film showed a response of 13.5 % at 623 K upon exposure to 24 ppm of NH3.
Aderemi A. Alabi, Johnson O. Aina, Adebambo O. Adewale and Abass A. Ajanaku
We assessed the effect of different land use types on the physical and chemical properties of soil. We analysed three cases. Nine soil samples were taken at different depths (0–10, 10–20 and 20–30 cm) from three locations, namely, sawmill, dumpsite and market. Analyses were carried out to determine the influences on the physical and chemical properties of the soil. All the land types had considerably high sand contents, with minor silt and clay. Available phosphorus and the exchangeable bases were significantly (p ≤ 0.05) affected by land use and soil depth. Moisture content (p ≤ 0.05) was significantly affected by land use, while bulk density (p ≤ 0.01) was significantly affected by soil depth. Soil organic matter and carbon were also generally low in all three locations. Consequently, ameliorative land management practices have to be adopted to prevent nutrient loss and land degradation.
Copper tin sulfide (Cu2SnS3) is a unique semiconductor, whose nanocrystals have attracted researchers’ attention for its tunable energy bandgap and wavelength in visible and near infrared range. Quantum dots which are fabricated from this material are highly suitable for optoelectronics and solar cell applications. This paper discusses the tunable energy bandgap, exciton Bohr radius and wavelength range of wurtzite structure of Cu2SnS3 quantum dots to assess the opportunity to use them in optoelectronics applications. The considerations show that the mole fraction of copper increases as energy bandgap decreases and tunable energy bandgap of this quantum dot material is inversely proportional to the wavelength.
Matej Babič, Miłosz Andrzej Huber, Elzbieta Bielecka, Metin Soycan, Wojciech Przegon, Ljubomir Gigović, Siniša Drobnjak, Dragoljub Sekulović, Ivan Pogarčić, George Miliaresis, Matjaž Mikoš and Marko Komac
Many problems in the analysis of natural terrain surface shapes and the construction of terrain maps to model them remain unsolved. Almost the whole process of thematic interpretation of aerospace information consists of a step-by-step grouping and further data conversion for the purpose of creating a completely definite, problematically oriented picture of the earth’s surface. In this article, we present application of a new method of drawing 3D visibility networks for pattern recognition and its application on terrain surfaces. For the determination of complexity of 3D surface terrain, we use fractal geometry method. We use algorithm for constructing the visibility network to analyse the topological property of networks used in complex terrain surfaces. Terrain models give a fast overview of a landscape and are often fascinating and overwhelmingly beautiful works by artists who invest all their interest and an immense amount of work and know-how, combined with a developed sense of the portrayed landscape, in creating them. At the end, we present modelling of terrain surfaces with topological properties of the visibility network in 3D space.
An aqueous colloidal solution was prepared at 80 °C and pH = 9 from suitable chemical compounds to produce zinc oxide (ZnO) crystals and thin films. The ZnO crystals were grown in the colloidal solution under special conditions. Their micrographs showed ZnO rods with hexagonal structure. The number of the rods, increased over time. The ZnO thin films were produced on glass substrates in the same colloidal solution using the chemical bath deposition (CBD) method in different deposition times. The produced films were post-annealed for about one hour at 400 °C. Crystalline structure, phase transitions and nanostructure of the films were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM). ZnO wurtzite structure was dominant, and by increasing the deposition time, the films became more crystalline. Nanostructure of the films changed from rod to wire and transformed into pyramid-like structures. Also, morphology of the films changed and re-nucleation ocurred. Optical reflectance was measured in the wavelength of 300 nm to 800 nm with a spectrophotometer. Other optical properties and optical band gaps were calculated using Kramers-Kronig relation on reflectivity curves. Second harmonic generation was calculated by Z-scan technique. Nonlinear refraction and real part of susceptibilities were obtained. Both positive and negative nonlinear refractions appeared in the ZnO films. It is important for the use in optoelectronic devices. Electronic properties were assessed by the full potential linearized augmented plane wave (FP-LAPW) method, within density functional theory (DFT). In this approach, the generalized gradient approximation (GGA) was used for the exchange-correlation potential calculation. The band gap structure and density of states were calculated.
Jian Chen, Xiongfei Li, Wei Li, Cong Li, Baoshan Xie, Shuowei Dai, Jian-Jun He and Yanjie Ren
Quasi-static uniaxial compressive tests of open-cell copper (Cu) foams (OCCF) were carried out on an in-situ bi-direction tension/compress testing machine (IBTC 2000). The effects of strain rate, porosity and pore size on the energy absorption of open-cell copper foams were investigated to reveal the energy absorption mechanism. The results show that three performance parameters of open-cell copper foams (OCCF), involving compressive strength, Young modulus and yield stress, increase simultaneously with an increase of strain rate and reduce with increasing porosity and pore size. Furthermore, the energy absorption capacity of OCCF increases with an increase of porosity and pore size. However, energy absorption efficiency increases with increasing porosity and decreasing pore size. The finite element simulation results show that the two-dimensional stochastic model can predict the energy absorption performance of the foam during the compressive process. The large permanent plastic deformation at the weak edge hole is the main factor that affects the energy absorption.
Co–Zn nanocrystalline ferrites with chemical composition Co0:5Zn0:5Fe2O4 were synthesized by sol-gel and combustion methods. The sol-gel method was carried out in two ways, i.e. based on chelating agents PVA and PEG of high and low molecular weights. In auto-combustion method, the ratio of citric acid to metal nitrate was taken as 1:1, while in sol-gel method the chelating agents were taken based on oxygen balance. All the three samples were studied by thermogravimetric and differential thermal analysis for the identification of phase formation and ferritization temperature. The synthesized samples were characterized by powder X-ray diffraction and FT-IR spectroscopy without any thermal treatment. The measured lattice constants and observed characteristic IR absorption bands of the three samples are in good agreement with the reported values showing the formation of a cubic spinel structure. The crystallite sizes of all samples were determined using high intensity peaks and W-H plot. Size-Strain Plot method was also implemented since two of the samples showed low crystallite sizes. The least crystallite size (5.5 nm) was observed for the sample CZVP while the highest (23.8 nm) was observed for the sample CZCA. Cation distribution was proposed based on calculated and observed intensity ratios of selected planes from X ray diffraction data. All structural parameters were presented using experimental lattice constant and oxygen positional parameter, and they correlated with FT-IR results. Magnetic measurements were carried out using vibrating sample magnetometer at room temperature to obtain the characteristic parameters such as saturation magnetization, coercivity, remanence, squareness ratio and Bohr magnetons. Among all, the sample synthesized via citric acid autocombustion method displayed a remarkably higher magnetization of 53 emu/g and the remaining two samples displayed low magnetization values owing to their smaller crystallite sizes.