Modelling equilibrium data for manganese(II) sorption onto manganese dioxide modified chalcedonite using the non-linear regression method

Open access

Modelling equilibrium data for manganese(II) sorption onto manganese dioxide modified chalcedonite using the non-linear regression method

Manganese dioxide is characterized by the acidic type of surface and high value of negative surface charge. It shows sorption and oxidation properties to such pollutants as heavy metals, radionuclides, arsenate(III), iodide. In the water conditioning technology it is used to modify various materials, including chalcedonite, which was the subject of the research presented in this paper. The manganese(II) equilibrium sorption was modeled using the non-linear regression method and basing on the Langmuir, Freundlich, Redlich-Peterson as well as pseudo-Langmuir isotherm equations. The determination of the isotherm equations parameters was run in two ways: by the minimization of the sum of the squared errors (SSE) as well as the minimization of the average relative error (ARE). The experimental data was best described in the Langmuir's isotherm equation, with the determination coefficient r2 = 0.916. The calculated parameters of the equation equaled: qm = 1.07 mg/g and b = 1.55 L//mg. The three-parameter equations of Redlich-Peterson and pseudo-Langmuir, assuming the possibility of multilayer sorption, came down to the Langmuir's equation. It serves as proof of monolayer sorption of manganese(II) onto manganese dioxide modified chalcedonite.

AL-DEGS Y., TUTUNJU M. F., SHAWABKEH R. A. 2000: The Feasibility of Using Diatomite and Mn-Diatomite for Remediation of Pb2+, Cu2+, and Cd2+ from Water. Separ. Sci. Technol. 35: 2299 -2310.

AL-DEGS Y., KHRAISHEH M. A. M., TUTUNJU M. F. 2001: Sorption of lead ions on diatomite and manganese oxides modified diatomite. Water Res., 35: 3724-3728.

ALLARD S., GUNTEN U., SAHLI E., NICOLAU R., GALLARD H. 2009: Oxidation of iodide and iodine on birnessite (δ-MnO2) in the pH range 4-8. Water Res. 43: 3417-3426.

ANIELAK A. M. 2006: Właściwości fizykochemiczne klinoptylolitu modyfikowanego ditlenkiem manganu. [The physicochemical properties of manganese dioxide-modified clinoptylolite]. Przem. Chem. 85: 487-491 [Engl. summ.].

BIELAŃSKI A. 2004: Podstawy chemii nieorganicznej. Wydawnictwo Naukowe PWN, Warszawa.

BOONFUENG T., AXE L., XU Y. 2005: Properties and structure of manganese oxide-coated clay. J. Colloid Interf. Sci. 281: 80-92.

DIAS A., SA R. G., SPITALE M. C., ATHAYDE M., CIMINELLI V. S. T. 2008: Microwave-hydrothermal synthesis of nanostructured Na-birnessites and phase transformation by arsenic(III) oxidation. Materials Research Bulletin 43: 1528-1538.

DRIEHAUS W., SEITH R., JEKEL M. 1995: Oxidation of arsenate(III) with manganese oxides in water treatment. Water Research 1: 297-305.

FENG Q., KANOH H., OOI K. 1999: Manganese oxide porous crystals. J. Mater. Chem. 9: 319-333.

FREUNDLICH H. M. F. 1906: Über die adsorption in lösungen. Z. Phys. Chem. 57A: 385-470.

FRITSCH S., POST J. E., NAVROTSKY A. 1997: Energetics of low-temperature polymorphs of manganese dioxide and oxyhydroxide. Geochim. Cosmochim. Act. 13: 2613-2616.

HAMDAOUI O., NAFFRECHOUX E. 2007a: Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon. Part I. Two-parameter models and equations allowing determination of thermodynamic parameters. J. Hazard. Mater. 147: 381-394.

HAMDAOUI O., NAFFRECHOUX E. 2007b: Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon. Part II. Models with more than two parameters. J. Hazard. Mater. 147: 401-411.

HAN R., ZOU W., WANG Y., ZHU L. 2007: Removal of uranium(VI) from aqueous solutions by manganese oxide coated zeolite: discussion of adsorption isotherms and pH effect. Journal of Environmental Radioactivity 93: 127-143.

HO Y. S. 2006: Isotherms for the sorption of lead onto peat: comparison of linear and non-linear methods. Pol. J. Environ. Stud. 15: 81-86.

HO Y. S., CHIU W. T., WANG C. C. 2005: Regression analysis for the sorption isotherms of basic dyes on sugarcane dust. Bioresour. Technol. 96: 1285-1291.

HU P.-Y., HSIEH Y.-H., CHEN J.-C., CHANG C.-Y. 2004: Characteristics of manganese-coated sand using SEM and EDAX analysis. J. Colloid Interf. Sci. 272: 308-313.

KANUNGO S. B., TRIPATHY S. S., RAJEEV 2004a: Adsorption of Co, Ni, Cu, and Zn on hydrous manganese dioxide from complex electrolyte solutions resembling sea water in major ion content. J. Colloid Interf. Sci 269: 1-10.

KANUNGO S. B., TRIPATHY S. S., MISHRA S. K., SAHOO B., RAJEEV 2004b: Adsorption of Co2+, Ni2+, Cu2+, and Zn2+ onto amorphous hydrous manganese dioxide from simple (1-1) electrolyte solutions. J. Colloid Interf. Sci 269: 11-21.

KOULOURIS G. 1995: Dynamic studies on sorption characteristics of 226Ra on manganese dioxide. Journal of Radioanalytical and Nuclear Chemistry 2: 269-279.

KOWAL A. L., ŚWIDERSKA-BRÓŻ M. 2009: Oczyszczanie wody. Podstawy teoretyczne i technologiczne, procesy i urządzenia. Wydawnictwo Naukowe PWN, Warszawa 2009.

LANGMUIR I. 1916: The constitution and fundamental properties of solids and liquids. J. Am. Chem. Soc. 38: 2221-2295.

LEE C.-I, YANG W.-F, HSIEH C.-I 2004: Removal of copper(II) by manganese-coated sand in a liquid fluidized-bed reactor. J. Hazard. Mater. B 114: 45-51.

MA S.-B., AHN K.-Y., LEE E.-S., OH K.-H., KIM K.-B. 2007: Synthesis and characterization of manganese dioxide spontaneously coated on carbon nanotubes. Carbon. 45: 375-382.

MALIYEKKAL S. M., SHARMA A. K., PHILIP L. 2006: Manganese-oxide-coated alumina: A promising sorbent for defluoridation of water. Water Res. 40: 3497-3506.

MICHEL M. M. 2008: Usuwanie jonów manganu(II) z roztworów wodnych na chalcedonicie naturalnym i modyfikowanym. [Removal of manganese(II) from aqueous solution by natural and modified chalcedonite]. Materials of VIIITh International Conference "Water Supply and Water Quality" Poznań-Gniezno, Poland, T. 1, p. 557-569 [Engl. summ.].

MICHEL M. M. 2009: Odmanganianie wody podziemnej na modyfikowanym chalcedonicie. Gaz, Woda i Technika Sanitarna 4: 22-26.

MICHEL M. M. 2011: Charakterystyka chalcedonitu ze złoża Teofilów pod kątem możliwości wykorzystania w technologii uzdatniania wody i oczyszczania ścieków. [Characteristics of chalcedonite from Teofilów deposit for possible use in technology of water and wastewater treatment]. Gospodarka Surowcami Mineralnymi 27: 49-67 [Engl. summ.].

MICHEL M. M., KIEDRYŃSKA L., TYSZKO E. 2008: Badania skuteczności odmanganiania wody podziemnej na modyfikowanym chalcedonicie i masie katalitycznej Purolite MZ-10. [Manganese removal from groundwater on modified chalcedonite and Purolite MZ-10 beds]. Ochrona Środowiska 3: 15-20 [Engl. summ.].

MOORE W. S., REID D. F. 1973: Extraction of radium from natural waters using manganese - impregnated acrylic fibers. J. Geophysical Res. 36: 8880-8886.

MURRAY J. W. 1974: The surface chemistry of hydrous manganese dioxide. J. Colloid Interf. Sci. 3: 357-371.

OLAŃCZUK-NEYMAN K. 2001: Mikroorganizmy w kształtowaniu jakości i uzdatnianiu wód podziemnych. Monografie Komitetu Inżynierii Środowiska PAN, Vol. 1, Wydawnictwo Politechniki Gdańskiej, Gdańsk.

PIECH A. 2007: Wykorzystanie diatomitów karpackich modyfikowanych powierzchniowo do usuwania arsenu z roztworów wodnych. [Utilisation of surface modified carpathian diatomites for arsenic removal from aqueous solution]. Zesz. Nauk. Politechniki Rzeszowskiej, Budownictwo i Inżynieria Środowiska 241: 49-56 [Engl. summ.].

RAJE N., SWAIN K. K. 2002: Purification of arsenic contaminated ground water using hydrated manganese dioxide. Journal of Radioanalitical and Nuclear Chemistry 1: 77-80.

RATAJCZAK T., WYSZOMIRSKI P. 1991: Charakterystyka mineralogiczno-surowcowa chalcedonitów spongiolitowych z Teofilowa nad Pilicą. [Mineralogical and technological characteristics of spongolithic chalcedonite of Teofilów on Pilica]. Gospodarka Surowcami Mineralnymi 7: 65-84 [Engl. summ.].

REDLICH O., PETERSON D. L. 1959: A useful adsorption isotherm. J. Phys. Chem. 63: 1024-1026.

SALARIRAD M. M., BEHNAMFARD A. 2011: Modeling of equilibrium data for free cyanide adsorption onto activated carbon by linear and non-linear regression methods. International Conference on Environment and Industrial Innovation, IPCBEE vol.12 (2011) © IACSIT Press, Singapore.

SU Q., PAN B., PAN B., ZHANG Q., ZHANG W., LV L., WANG X., WU J., ZHANG Q. 2009: Fabrication of polymer-supported nano-sized hydrous manganese dioxide (HMO) for enhanced lead removal from waters. Science of the Total Environment 407: 5471-5477.

ŚWIĄTCZAK J., SKOTAK K., BRATKOWSKI J., WITCZAK S., POSTAWA A. 2008: Metale i substancje towarzyszące w wodach przeznaczonych od spożycia w Polsce. [Metals and related substances in drinking waters in Poland]. Materials of VIIIth International Conference "Water Supply and Water Quality" Poznań-Gniezno, Poland, T. 1, p. 289-301 [Engl. summ.].

TAFFAREL S. R., RUBIO J. 2010: Removal of Mn2+ from aqueous solution by manganese oxide coated zeolite. Minerals Engineering 23: 1131-1138.

TRIPATHY S. S., BERSILLON J.-L., GOPAL K. 2006: Adsorption of Cd2+ on hydrous manganese dioxide from aqueous solutions. Desalination 194: 11-21.

Annals of Warsaw University of Life Sciences – SGGW. Land Reclamation

The Journal of Warsaw University of Life Sciences

Journal Information

Metrics

All Time Past Year Past 30 Days
Abstract Views 0 0 0
Full Text Views 142 139 9
PDF Downloads 53 53 3