The usefulness of Mehlich 3 and 1 M HCl extractant to assess copper deficiency in soil for environmental monitoring purpose / Przydatność ekstrahentów Mehlich 3 i 1 M HCl do oceny niedoborów miedzi w glebie pod kątem monitoringu środowiska

Open access

Abstract

The aim of this study was to compare two soil tests, 1 M HCl and Mehlich 3, to extract phytoavailable Cu forms from the soil. The evaluation of tests was performed on the basis of the correlation between soil Cu extracted by the studied extractants, and plant Cu or yield of a test plant. Data for the calculation originated from the microplot experiment with winter wheat. The experiment included three soils that differed in texture, pH level and copper content. Each of the soil was fertilized with five doses of Cu: 0, 4, 8, 12 and 16 kg • ha−1 against two pH levels. The results showed a strong correlation between the two soil tests and their similar usefulness for the extraction of copper available to plants. On the basis of Pearson correlation coefficients and equation of simple regression, it was found that Mehlich 3 was slightly more useful for heavier soils with higher pH, whereas 1 M HCl was better suitable for acid sandy soil.

ARAỦJO DO NASCIMENTO, CW, FONTES, RLF, MELICIO, ACFD 2003, ‘Copper availability as related to soil copper fractions in oxisols under liming’, Scientia Agricola 60, vol. 1, pp. 167-173.

BORECZEK, B, SUMOREK-GOŁĄBEK, A, JANDA, B 2012, ‘Wielopierwiastkowa analiza gleb metodą Mehlicha III’, Główne Laboratorium Analiz Chemicznych (IUNG-PIB), pp. 1-17. Materiały niepublikowane.

BRENNAN, D, BOLLAND, DA 2006, ‘Comparing soil and tissue testing of copper for early growth of wheat’, Communications inSoil Science and Plant Analysis 39, vol. 9-10, pp. 1451-1470.

BRENNAN, D, COULTER, B, MULLEN, G, COURTNEY, R 2008, ‘Evaluation of Mehlich 3 for extraction of copper and zinc from Irish grassland soils and for prediction of herbage content’, Communications in Soil Science and Plant Analysis, vol. 39, pp. 1943-1962.

BRUN, LA, MAILLET, J, HINSINGER, P, PẺPIN, M 2001, ‘Evaluation of copper availability to plants in copper-contaminated vineyard soils’, Environmental Pollution, vol. 111, pp. 293-302.

CHILIMBA, ADC, MUGHOGHO, SK, WENDT, J 1999, ‘Mehlich 3 or modified Olsen for soil testing in Malawi’, Communicationsin Soil Science and Plant Analysis 30, vol. 7-8, pp. 1231-1250.

DROZD, J, LICZNAR, M, LICZNAR, SE, WEBER, J 2002, Gleboznawstwo z elementami mineralogii i petrografii. Wrocław, pp. 133-171.

FONSECA, AF, CAIRES, EF, BARTH, G 2010, ‘Extraction methods and availability of micronutrients for wheat under a no-till system with a surface application of lime’, Scientia Agricola 67, vol. 1, pp. 60-70.

FOTYMA, M, MERCIK, S, FABER, A 1987, Chemiczne podstawy żyzności gleb i nawożenia. Państwowe Wydawnictwo Rolnicze i Leśne. Warszawa, pp. 199-216.

GARCIA, A, DE IORIO, AF, BARROS, M, BARGIELA, M, RENDINA, A 1997, ‘Comparison of soil tests to determine micronutrients status in Argentina soils’, Communications in Soil Scienceand Plant Analysis 28, vol. 19-20, pp. 1777-1792.

GEMBARZEWSKI, H, KORZENIOWSKA, J 1990, ‘Simultaneous extraction of B, Cu, Fe, Mn, Mo and Zn from mineral soils, and an estimation of the results’, Agrobiological Research, vol. 43, pp. 115-127.

GEMBARZEWSKI, H, KORZENIOWSKA, J 1996, ‘Wybór metody ekstrakcji mikroelementów z gleby i opracowanie liczb granicznych przy użyciu regresji wielokrotnej’, Zeszyty ProblemowePostępów Nauk Rolniczych, vol. 434, pp. 353-364.

KARCZEWSKA, A 2002, Metale ciężkie w glebach zanieczyszczonych emisjami hut miedzi - formy i rozpuszczalność. Rozprawa habilitacyjna. Zeszyty Naukowe AR we Wrocławiu. Wydział Rolniczy. Wrocław, 432.

KORZENIOWSKA, J 2008a, Potrzeby nawożenia pszenicy cynkiem, miedzią i borem w warunkach glebowo - klimatycznych Polski. Monografie i Rozprawy Naukowe. IUNG-PIB, 20.

KORZENIOWSKA, J 2008b, ‘Znaczenie niedoboru miedzi w uprawie pszenicy’, Postępy Nauk Rolniczych, vol. 4-5, pp. 15-31.

KHAN, MAR, BOLAN, NS, MACKAY, AD 2005, ‘Soil test to predict the copper availability in pasture soils’, Communications in SoilScience and Plant Analysis 36, vol. 17-18, pp. 2601-2624.

LIU, J, LIAO, Z, HU, C, SUN, WQX, TAN, Q 2011, ‘Relationship between Mehlich-3, ASI and routine methods of soil available nutrients analysis for paddy soils in China’, Journal of Food,Agriculture and Environment 9, vol. 1, pp. 516-520.

LOIDE, V, NỎGES, M, REBANE, J 2005, ‘Assessment of the agrochemical properties of the soil using the extraction solution Mehlich 3 in Estonia’, Agronomy Research 3, vol. 1, pp. 73-80.

MCLAUGHLIN, MJ, ZARCINAS, BA, STEVENS, DP, COOK, N 2000, ‘Soil testing for heavy metals’, Communications in SoilScience and Plant Analysis 31, vol. 11-14, pp. 1661-1700.

MEHLICH, A 1984, ‘Mehlich 3 soil test extractant: A modification of Mehlich 2 extractant’, Communications in Soil Science andPlant Analysis 15, vol. 12, pp. 1409-1416.

MENZIES, NW, DONN, MJ, KOPITTKE, PM 2007, ‘Evaluation of extractants for estimation of the phytoavailable trace metals in soils’, Environmental Pollution, vol. 145, pp. 121-130.

RAO, CRM, SAHUQUILLO, A, LOPEZ SANCHEZ, JF 2008, ‘A review of the different methods applied in environmental geochemistry for single and sequential extraction of trace elements in soils and related materials’, Water, Air, & Soil Pollution, vol. 189, pp. 291-333.

RODRIGUEZ, B, RAMIREZ, R 2005, ‘A soil test for determining available copper in acidic soils of Venezuela’, Intercjencia 30, vol. 6, pp. 361-364.

SARTO, MVM, STEINER, F, LANA, MC 2011, ‘Assessment of micronutrient extractants from soils of Paranả, Brazil’, RevistaBrasileira de Ciência do Solo, vol. 35, pp. 2093-2103.

SILVA, MAG, MUNIZ, AS, MATA, JDV, CEGANA, ACV 2003, ‘Extratores para a quantificação do zinco e do cobre em solos cultivados com soja’, Acta Scientarum Agronomy, vol. 26, pp. 361-366.

STANISŁAWSKA - GLUBIAK, E, KORZENIOWSKA, J 2010, ‘Usefulness of 1 mol HCl • dcm−3 extractant to assess copper, zinc and nickel contamination in sandy soil’, Fresenius EnvironmentalBulletin, vol. 19, pp. 589-593.

URE, AM 1991, ‘Trace element speciation in soils, soil extracts and solutions’, Microchimica Acta [Wien], vol. 2, pp. 49-57.

WALWORTH, JL, GAVLAK, RG, PANCIERA, MT 1992, ‘Mehlich 3 extractant for determination of available B, Cu, Fe, Mn and Zn in cryic Alaskan soils’, Canadian Journal of Soil Science, vol. 72, 517-526.

ZBIRAL, J, NEMEC, P 2000, ‘Integrating of Mehlich 3 extractant into the Czech soil. Testing scheme’, Communications in SoilScience and Plant Analysis, vol. 31, 2171-2182.

Journal Information

CiteScore 2017: 0.26

SCImago Journal Rank (SJR) 2017: 0.137
Source Normalized Impact per Paper (SNIP) 2017: 0.211

Cited By

Metrics

All Time Past Year Past 30 Days
Abstract Views 0 0 0
Full Text Views 138 138 10
PDF Downloads 42 42 5