Synthesis of V2O3/C composites with different morphologies by a facile route and phase transition properties of the compounds

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V2O3 and amorphous carbon composites (V2O3/C composites) with different morphologies (e.g. nanospheres, nanorods and nanosheets) were, for the first time, successfully synthesized by a facile hydrothermal route and subsequent calcination. The as-obtained samples were characterized by X-ray powder diffraction (XRD), energy dispersive spectrometery (EDS), elemental analysis (EA), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The morphology of V2O3/C composites could be easily controlled by varying the reaction time, and, as a result, V2O3/C composites with nanospheres, nanorods and nanosheets were selectively synthesized. Furthermore, the phase transition property of V2O3/C composites was measured by differential scanning calorimetry (DSC), suggesting that V2O3/C composites exhibit the phase transition similar to V2O3, which could expand the potential applications of materials related to V2O3 in the future.

[1] Qi J., Ning G., Hua R., Tian M., Liu S., Mater. Sci.-Poland, 30 (2012), 151.

[2] Zhang Y., Huang Y., Zhang J., Wu W., Niu F., Zhong Y., Liu X., Liu X., Huang C., Mater. Res. Bull., 47 (2012), 1978.

[3] Zhang Y., Fan M., Liu X., Xie G., Li H., Huang C., Solid State Commun., 152 (2012), 253.

[4] Zhang Y., Li W., Fan M., Zhang F., Zhang J., Liu X., Zhang H., Huang C., Li H., J. Alloy. Compd., 544 (2012), 30.

[5] Surnev S., Ramsey M.G., Netzer F.P., Prog. Surf. Sci., 73 (2003), 117.

[6] Zhang Y., Zhang J., Fan M., Long Y.A., Zhong Y., Liu X., Huang C.H.I., B. Mater. Sci., 36 (2013), 345.

[7] Zhang Y., Chen C., Wu W., Niu F., Liu X., Zhong Y., Cao Y., Liu X., Huang C., Ceram. Int., 39 (2013), 129.

[8] Liu J., Wang X., Peng Q., Li Y., Adv. Mater., 17 (2005), 764.

[9] Zhang Y., Zhang J., Zhang X., Huang C., Zhong Y., Deng Y., Mater. Lett., 92 (2013), 61.

[10] Zhang Y., Zhang J., Zhang X., Deng Y., Zhong Y., Huang C., Liu X., Liu X., Mo S., Ceram. Int., 39 (2013), 8363.

[11] Parkin I.P., Manning T.D., J. Chem. Educ., 83 (2006), 393.

[12] Zhang Y., Zhang J., Zhang X., Mo S., Wu W., Niu F., Zhong Y., Liu X., Huang C., Liu X., J. Alloy. Compd., 570 (2013), 104.

[13] Zhang Y., Fan M., Niu F., Wu W., Huang C., Liu X., Li H., Liu X., Curr. Appl. Phys., 12 (2012), 875.

[14] Xu L., Zhang Y., Deng Y., Zhong Y., Mo S., Cheng G., Huang C., Mater. Res. Bull., 48 (2013), 3620.

[15] Zhang Y., Liu X., Xie G., Yu L., Yi S., Hu M., Huang C., Mater. Sci. Eng. B-Adv., 175 (2010), 164.

[16] Zhang Y., Fan M., Niu F., Zhong Y., Huang C., Liu X., Wang B., Li H., Micro Nano Lett., 6 (2011), 888.

[17] Foex M., CR Chim., 223 (1946), 1126.

[18] Mcwhan D.B., Remeika J.P., Phys. Rev. B, 2 (1970), 3734.

[19] Hendrix B.C., Wang X., Chen W., Cui W.Q., J. Mater. Sci., 3 (1992), 113.

[20] Seikh M.M., Narayana C., Sood A.K., Murugavel P., Kim M.W., Metcalf P.A., Honig J.M., Rao C.N.R., Solid State Commun., 138 (2006).

[21] Kokabi H.R., Rapeaux M., Aymami J.A., Desgardin G., Mater. Sci. Eng. B-Adv., 38 (1996), 80.

[22] Dernier P.D., Marezio M., Phys. Rev. B, 2 (1970), 3771.

[23] Zheng C.M., Zhang X.M., He S., Fu Q., Lei D.M., J. Solid State Chem., 170 (2003), 221.

[24] Ballarini N., Battisti A., Cavani F., Cericola A., Lucarelli C., Racioppi S., Arpentinier P., Catal. Today, 116 (2006), 313.

[25] Pan Y., Wu G.Z., Yi X.S., J. Mater. Sci., 29 (1994), 5757.

[26] Zhang Y., Zhang J., Nie J., Zhong Y., Liu X., Huang C., Micro Nano Lett., 7 (2012), 782.

[27] Pinna N., Antonietti M., Niederberger M., Colloid. Surface. A, 250 (2004), 211.

[28] Zhang K.F., Sun X.Z., Louu G.W., Liu X., Li H.L., Su Z.X., Mater. Lett., 59 (2005), 2729.

[29] Ramana C.V., Utsunomiya S., Ewing R.C., Becker U., Solid State Commun., 137 (2006), 645.

[30] Sediri F., Gharbi N., Mater. Sci. Eng. B-Adv., 123 (2005), 136.

[31] Teghil R., D’Alessio L., De Bonis A., Galasso A., Ibris N., Salvi A.M., Santagata A., Villani P., J. Phys. Chem. A, 113 (2009), 14969.

[32] Liu X.H., Zhang Y.F., Yi S.P., Huang C., Liao J., Li H.B., Xiao D., Tao H.Y., J. Supercrit. Fluid., 56 (2011), 194.

[33] Corr S.A., Grossman M., Shi Y.F., Heier K.R., Stucky G.D., Seshadri R., J. Mater. Chem., 19 (2009), 4362.

[34] Xu Y., Zheng L., Wu C., Qi F., Xie Y., Chem.-Eur. J., 17 (2011), 384.

[35] Chen J.A., Liu X.A., Su Z.X., Micro Nano Lett., 6 (2011), 102.

[36] Odani A., Pol V.G., Pol S.V., Koltypin M., Gedanken A., Aurbach D., Adv. Mater., 18 (2006), 1431.

[37] Sun Y.F., Jiang S.S., Bi W.T., Wu C.Z., Xie Y., J. Power Sources, 196 (2011), 8644.

[38] Zhang Y., Fan M., Liu X., Huang C., Li H., Eur. J. Inorg. Chem., 2012 (2012), 1650.

[39] Zhang Y., Zhang F., Yu L., Fan M., Zhong Y., Liu X., Mao Y., Huang C., Colloid. Surface. A, 396 (2012), 144.

[40] Zhang Y., Fan M., Hu L., Wu W., Zhang J., Liu X., Zhong Y., Huang C., Appl. Surf. Sci., 258 (2012), 9660.

[41] Rice C.E., Robinson W.R., J. Solid State Chem., 21 (1977), 145.

[42] Zhang Y., Liu X., Chen D., Yu L., Nie J., Yi S., Li H., Huang C., J. Alloy. Compd., 509 (2011), L69.

[43] Zhang Y., Liu X., Nei J., Yu L., Zhong Y., Huang C., J. Solid State Chem., 184 (2011), 387.

[44] Zhang Y., Zhou M., Fan M., Huang C., Chen C., Cao Y., Li H., Liu X., Curr. Appl. Phys., 11 (2011), 1159.

[45] Gilson T.R., Bizri O.F., Cheetham N., Dalton T., (1973), 291.

[46] Ros T.G., Van Dillen A.J., Geus J.W., Koningsberger D.C., Chem.-Eur. J., 8 (2002), 1151.<1151::AID-CHEM1151>3.0.CO;2-#

[47] Llie A., Durkan C., Milne W.I., Welland M.E., Phys. Rev. B, 66 (2002), 045412/1.

[48] Dresselhaus M.S., Dresselhaus G., Eklund M.A.P., Raman Scattering in Carbon Materials, in: Pelletier M.J. (Ed.), Analytical Application of Raman Spectroscopy, Wiley-Blackwell Publishing, Oxford, 1999, p. 367.

[49] Zhang Y., Fan M., Wu W., Hu L., Zhang J., Mao Y., Huang C., Liu X., Mater. Lett., 71 (2012), 127.

[50] Zhang Y., Zhang J., Zhong Y., Yu L., Deng Y., Huang C., Liu X., Appl. Surf. Sci., 263 (2012), 124.

[51] Sun X., Li Y., Angew. Chem. Int. Edit., 43 (2004), 597.

[52] Zhang Y., Fan M., Zhou M., Huang C., Chen C., Cao Y., Xie G., Li H., Liu X., B. Mater. Sci., 35 (2012), 369.

[53] Zhang Y., Chen C., Zhang J., Hu L., Wu W., Zhong Y., Cao Y., Liu X., Huang C., Curr. Appl. Phys., 13 (2013), 47.

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