Geochemical features of fossil fuel contaminants found in urban wastes (Siemianowice Śląskie, Poland)

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Geochemical features of fossil fuel contaminants found in urban wastes (Siemianowice Śląskie, Poland)

In sludge samples collected in the "Centrum" wastewater treatment plant in Siemianowice Śląskie, Poland, the composition of aliphatic- and aromatic hydrocarbons and polar compound fractions were investigated by gas chromatography-mass spectrometry (GC-MS). Samples collected in accordance with Polish standards were extracted, the extracts were separated into fractions with preparative thin layer chromatography (TLC), which next were investigated by GC-MS. The following compound groups of the geochemical origin were identified: n-alkanes in the range of n-C14 to n-C.39, acyclic isoprenoids (mainly pristane and phytane), steranes, tri- and pentacyclic triterpanes. Based on the distribution of biomarkers and their parameters, it was established that the dominant component of extractable organic matter in sluge is petroleum material of an unspecified origin. Its geochemical features indicate that its most likely source was crude oil (or its products) of a relatively high degree of thermal maturity (catagenic stage of thermal evolution corresponding to vitrinite reflectance 0.7-0.8%). Aromatic hydrocarbons probably originated from petroleum also, though some of them can be attributed to the products of combustion or to sources such as bituminous coals, the ash from coal/biofuel combustion or coal wastes stored nearby.

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  • Barthlott W. Neinhuis C. Cutler D. Ditsch F. Meusel I. Theisen I. & Wilhelmi H. (1998). Classification and terminology of plants epicuticular waxes. Botanical Journal of the Linnean Society 126 237-260. DOI: 10.1111/j.1095-8339.1998.tb02529.x.

  • Berset J.D. & Holzer R. (1999). Quantitative determination of polycyclic aromatic hydrocarbons polychlorinated biphenyls and organochlorine pesticides in sewage sludges using supercritical fluid extraction and mass spectrometric detection. Journal of Chromatography A 852 545-558. DOI: 10.1016/S0021-9673(99)00641-X.

  • Bodzek D. & Janoszka B. (1999). Comparison of polycyclic aromatic compounds and heavy metals contents in sewage sludges from industrialized and non-industrialized region. Water Air Soil Pollution 111 359-369. DOI: 10.1023/A:1005066327712.

  • Bray E.E. & Evans E.D. (1961). Distribution of n-paraffin as a clue to recognition of source beds. Geochimica et Cosmochimica Acta 22 2-15. DOI: 10.1016/0016-7037(61)90069-2.

  • Didyk B.M. Simoneit B-T. Brassell S.C. & Eglinton G. (1978). Organic geochemical indicators of paleoenvironmental conditions of sedimentation. Nature 272 217-222.

  • Dong J-Z. Vorking W.P. & Lee M.L. (1993). Origin of long-chain alkylcyclohexanes and alkylbenzenes in a coal-bed wax. Geochimica et Cosmochimica Acta 57 837-849.

  • Durand C. Ruban V. Ambles A. & Oudot J. (2004). Characterization of the organic matter of sludge: determination of lipids hydrocarbons and PAHs from road retention/infiltration ponds in France. Environmental Pollution 132 375-384. DOI: 10.1016/j.envpol.2004.05.038.

  • Eglinton G. & Hamilton R.J. (1967). Leaf epicuticular waxes. Science 156 1322-1335. DOI: 10.1126/science.156.3780.1322.

  • Eriksson E. Christensen N. Schmidt J.E. & Ledin A. (2008). Potential priority pollutants in sewage sludge. Desalination 226 371-388. DOI:10.1016/j.desal.0000.00.000.

  • Hartmann L. (1996). Biologiczne oczyszczanie ścieków. Warszawa: Wydawnictwo Instalator Polski.

  • Huang W.-Y. & Meinschein W.G. (1979). Sterols as ecological indicators. Geochimica et Cosmochimica Acta 43 739-745. DOI: 10.1016/0016-7037(79)90257-6.

  • International Flavors & Fragrances (2007) Galaxolide® 50 DPG. 134678-hexahydro-466788-hexamethylcyclopenta-gamma-2-benzopyran. Retrievied April 19 2011 from

  • Kowal A.L. (1997). Odnowa wody: podstawy teoretyczne procesów (2nd ed. corrected). Wrocław: Oficyna Wydawnicza Politechniki Wrocławskiej.

  • Lewis M.D. Kleinkopf G.E. & Shetty K.K. (1997). Dimethylnaphthalene and diisopropylnaphthalene for potato sprout control in storage: 1. Application methodology and efficacy. American Journal of Potato Research 74 183-197. DOI: 10.1007/BF02851597.

  • Leythauser D. Schwartzkopf Th. (1985). The pristane/n-heptadecane ratio as an indicator for recognition of hydrocarbon migration effects. Organic Geochemistry 10 191-197. DOI: 10.1016/0146-6380(86)90022-7

  • Marchal R. Penet S. Solano-Serena F. & Vandecasteele J.P. (2003). Gasoline and diesel oil biodegradation. Oil & Gas Science and Technology - Rev. IFP 58 441-448. DOI: 10.2516/ogst:2003027.

  • Miksch K. & Sikora J. (2010). Biotechnologia ścieków. Warszawa: Wydawnictwo Naukowe PWN.

  • Noble R.A. Aleksander R. Kagi R.I. & Knox J. (1986). Identification of some diterpenoid hydrocarbons in petroleum. Organic Chemistry 10 825-829. DOI: 10.1016/S01 46-6380(86)80019-5.

  • Oil Chem Technologies (2010). Anionic surfactants. New Arylalkyl Sulfonates (AASA). Retrieved April 19 2011 from

  • Otto A. & Wilde V. (2001). Sesqui- di- and triterpenoids as chemosystematic markers in extant conifers: a review. Botanical Review 67 141-238. DOI: 10.1007/BF02858076.

  • Palmer S.E. (1993). Effect of Biodegradation and Water Washing on Crude Oil Composition in Organic Geochemistry Principles and Applications. In M.H. Engel & S.A. Macko (Eds.) New York: Plenum Press.

  • Pawelczyk-Szpilowa M. (1980). Ćwiczenia z mikrobiologii wody i ścieków. Warszawa: Wydawnictwo Naukowe PWN.

  • Peters K.E. Walters C.C. & Moldowan J.M. (2005). The Biomarker Guide (2nd ed.). Cambridge Cambridge University Press.

  • Polski Komitet Normalizacyjny (National Standards Body in Poland). (1988). Woda i ścieki - Ogólne zasady pobierania próbek do badań fizycznych chemicznych i biologicznych - Utrwalanie i przechowywanie próbek (Polish Standard: Water and sewage - General principles of sampling for physical chemical and biological analyses - Sample preservation and storage). PN-C-04632-04:1988. Warszawa.

  • Radke M. Welte D.H. & Willsch H. (1986). Maturity parameters based on aromatic hydrocarbons: influence of organic matter type. Organic Geochemistry 10 51-63. DOI: 10.1016/0146-6380(86)90008-2.

  • Scheffler K. (2004). Reconstruction of sedimentary environment and climate conditions by multi-geochemical investigations of Late Palaeozoic glacial to postglacial sedimentary sequences from SW-Gondwana. Dissertation zur Erlangung des Doktorgrades der Mathematisch-Naturwissenschaftlichen Fakultät der Rheinischen Fredrich-Wilhelms-Univeristät Bonn

  • Scott M.J. & Jones M.N. (2000). The biodegradation of surfactants in the environment. Biochimica et Biophysica Acta 1508 235-251. DOI:10.1016/S0304-4157(00)00013-7.

  • Seifert W.K. & Moldowan J.M. (1980). The effect of thermal stress on source-rock quality as measured by hopane stereochemistry. Physics and Chemistry of the Earth 12 229-237. DOI: 10.1016/0079-1946(79)90107-1.

  • Stevens J.L. Northcott G.L. Stern G.A. Tomy T.G. & Jones K.C. (2003). PAHs PCBs PCNs Organochlorine Pesticides Synthetic Musks and Polychlorinated n-Alkanes in U.K. Sewage Sludge: Survey Results and Implications. Environment Science and Technology 37 462-467. DOI: 10.1021/es020161y.

  • Tissot B.P. & Welte D.H. (1984). Petroleum formation and occurrence. Berlin: Springer-Verlag.

  • Wang Z. & Fingas M. (1999). Oil spill identification. Journal of Chromatography A 843 369-441. DOI: doi:10.1016/S0021-9673(99)00120-X.

  • Wiley J. (2000). The Wiley/NBS Registry of Mass Spectral Data. New York: J Wiley and Sons.

  • Zhang K. Noonan G.O. & Begley T.H. (2008). Determination of 26-diisopropylnaphthalene (DIPN) and n-dibutylphthalate (DBP) in food and paper packaging materials from US marketplaces. Food Additives and Contaminants 25(11) 1416-1423. DOI: 10.1080/02652030802163380.

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