The sensitivity of sensor structures with oxide graphene exposed to selected gaseous atmospheres

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The paper presents the results of investigations on the resistive structure with a graphene oxide (GO) sensing layer. The effects of dangerous gases (hydrogen and nitrogen dioxide) on the structure were studied; the resistance changes were examined during the flow of the selected gas in the atmosphere of synthetic air. Measurements were performed with a special emphasis on the detection of low concentrations of the analyzed gases. The reactions of the sensing structure to the effect of nitrogen and synthetic air at different humidity were also tested. Much attention was also paid to the fast response of the sensor to the changes in the gas atmosphere. The thin palladium layer (~2 nm) has been applied in order to improve the sensing properties of the structure. The investigations were performed in the temperature range from RT to 120°C and the analyzed gases in synthetic air were batched alternately with pure synthetic air.

[1] M. Urbańczyk, Gaseous Sensors with Surface Acoustic Waves, SUT, Gliwice, 2011, (in Polish).

[2] Z. Bielecki, J. Janucki, A. Kawalec, J. Mikolajczuk, N. Palka, M. Pasternak, T. Pustelny, T. Stacewicz, and J. Wojtas, “Sensors and systems for the detection of expolosive devices - an overview”, Metrol. Meas. Syst XIX (1), 3-28 (2012).

[3] L.S. Zhang, W.D. Wang, X.Q. Liang, W.S. Chu, W.G. Song, W. Wang, and Z. Wu, “Characterization of partially reduced grapheme oxide as room temperature sensor for H2”, Nanoscale 3, 2458-2460 (2011).

[4] B.H. Chu, J. Nicolosi, C.F. Lo, W. Strupiński, S.J. Pearton, and F. Ren, “Effect of coated platinum thickness on hydrogen detection sensitivity of graphene- based sensors”, Electrochemicaland Solid-State Letters 14 (7), K43-K45 (2011).

[5] Y. Zhu, S. Murali, W. Cai, X. Li, J.W. Suk, J.R. Potts, and R.S. Ruoff, “Graphene and grpgene oxide: synthesis, properties, and applications”, Adv. Mater. 22, 3906-3924 (2010).

[6] C. Tyszkiewicz, P. Karasiński, and R. Rogoziński, “Sensitive films for optical detection of ammonia and nitrogen dioxide”, Acta Physica Polonica A 122, 915-920 (2012).

[7] T. Pustelny, M. Procek, E. Maciak, A. Stolarczyk, S. Drewniak, M. Urbańczyk, M. Setkiewicz, K. Gut, and Z. Opilski, “Gas sensors based on nanostructures of semiconductors ZnO and TiO2”, Bull. Pol. Ac.: Tech. 60 (4), 853-859 (2012).

[8] E. Hill, A. Vijayaraghvan, and K. Novoselov, “Graphene sensors”, IEEE Sensors J. 11 (12), 3161-3170 (2011).

[9] A. Kaniyoor, R.I. Jafri, T. Arockiadoss, and S. Ramaprabhu, “Nanostructures Pt decorated graphene and multi walled carbon nanotube based room temperature hydrogen gas sensor”, Nanoscale 1, 382-386 (2009).

[10] T. Pustelny, M. Setkiewicz, S. Drewniak, E. Maciak, A. Stolarczyk, M. Procek, M. Urbańczyk, K. Gut, Z. Opilski, I. Pasternak, and W. Strupiński, “The influence of humidity on the resistance structures with graphene sensor layer”, Acta PhysicaPolonica A 122, 870-873 (2012).

[11] M. Gautam and A. Jayatissa, “Gas sensing properties of graphene synthesized by chemical vapor deposition”, MaterialsScience and Engineering C 31(7), 1405-1411 (2011).

[12] U. Lange, T. Hirsch, V.M. Mirsky, and O.S. Wolfbeis, “Hydrogen sensor based on a grapheme-palladium nanocomposite”, Electrochimica Acta 56, 3707-3712 (2011).

[13] M. Gautam and A.H. Jayatissa, “Gas sensing properties of grapheme synthesized by chemical vapor deposition”, MaterialsScience and Engineering C 31, 1405-1411 (2011).

[14] Ch.H. Lu, H.H. Yang, C.L. Zhu, X. Chen, and G.N. Chen, “A graphene oxide platform for sensing biomolecules”, Electroanalysis 22 (10), 1027-1036 (2010).

[15] G. Lu, L.E. Ocola, and J. Chen, “Reduced grapheme oxide for room-temperature gas sensors”, online, 20/445502, 1-9 (2009).

[16] B.H. Chu, C.F. Lo, J. Nicolosi, C.Y. Chang, V. Chen, W. Strupinski, S.J. Pearton, and F. Ren, “Hydrogen detection using platinum coated graphene grown on SiC”, Sensors andActuators B 157, 500-503 (2011).

[17] M. Urbanczyk, E. Maciak, K. Gut, T. Pustelny, and W. Jakubik, “Layered thin film nanostructures of Pd/WO3−x as resistance gas sensors”, Bull. Pol. Ac.: Tech. 59 (4), 401-407 (2011).

Bulletin of the Polish Academy of Sciences Technical Sciences

The Journal of Polish Academy of Sciences

Journal Information

IMPACT FACTOR 2016: 1.156
5-year IMPACT FACTOR: 1.238

CiteScore 2016: 1.50

SCImago Journal Rank (SJR) 2016: 0.457
Source Normalized Impact per Paper (SNIP) 2016: 1.239

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