Optimization of Sigma Phase Precipitates with Respect to the Functional Properties of Duplex Cast Steel
The paper presents the results of examination concerning optimization of the σ phase precipitates with respect to the functional properties of ferritic-austenitic cast steel. The examined material comprised two grades of corrosion-resistant cast steel, namely GX2CrNiMoN25-6-3 and GX2CrNiMoCuN25-6-3-3, used for example in elements of systems of wet flue gas desulphurisation in power industry. The operating conditions in media heated up to 70°C and containing Cl- and SO4 ions and solid particles produce high erosive and corrosive wear. The work proposes an application of the σ phase as a component of precipitation strengthening mechanism in order to increase the functional properties of the material. Morphology and quantities of σ phase precipitates were determined, as well as its influence on the erosion and corrosion wear resistance. It was shown that annealing at 800°C or 900°C significantly improves tribological properties as compared with the supersaturated state, and the best erosion and corrosion wear resistance achieved due to the ferrite decomposition δ → γ' + σ was exhibited in the case of annealing at the temperature of 800°C for 3 hours.
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